查看“︁D4sp杂化”︁的源代码

{{noteTA
|T=zh-hans:d<sup>4</sup>sp杂化; zh-hant:d<sup>4</sup>sp混成;
|1=zh-hans:轨道; zh-hant:軌域;
|2=zh-hans:杂化; zh-hant:混成;
|G1=Chemistry
}}
{{Infobox OH
| name = d<sup>4</sup>sp杂化
| element = 钒
| electron configuration = 
<math>
V^{3+*}\;[Ar]3d^2
\frac{\color{White}/}{(d^4sp)^6}
\frac{\color{White}/}{4p}
</math>
| s orbital = 1
| p orbital = 1
| d orbital = 4
| f orbital = 
| B = 
| C = 
| N = 
| O = 
| P = 
| S = 
| V = [V(H<sub>2</sub>O)<sub>6</sub>]<sup>3-</sup><ref name="配位化学">{{cite web| title =配合物的化学键理论：杂化轨道与空间构型的关系| work =配位化学| accessdate =2012-01-30| url =http://jpkc.yzu.edu.cn/course2/yjhx/peiweihuaxue/第三章%20%20配合物的化学键理论1.pdf| language =zh| deadurl =yes| archiveurl =https://web.archive.org/web/20160304074926/http://jpkc.yzu.edu.cn/course2/yjhx/peiweihuaxue/%E7%AC%AC%E4%B8%89%E7%AB%A0%20%20%E9%85%8D%E5%90%88%E7%89%A9%E7%9A%84%E5%8C%96%E5%AD%A6%E9%94%AE%E7%90%86%E8%AE%BA1.pdf| archivedate =2016-03-04}}</ref>
| Fe = 
| Co = 
| Ni = 
| Cu = 
| Pd = 
| Pt = 
| other = Re(S<sub>2</sub>C<sub>2</sub>Ph<sub>2</sub>)<sub>3</sub><ref name = "配位化学"/>、[[二硒化钼|MoSe<sub>2</sub>]]<ref>{{cite journal
 | author = V.G. Bhide and B.A. Patki
 | title = X-ray spectroscopic study of zirconium and molybdenum diselenides
 | journal = Pramana
 | volume = 2
 | issue = 5
 | pages = 290-297
 | ISSN = 0304-4289
 | doi = 10.1007/BF02847086
 | url = http://www.springerlink.com/content/e4h8q47386nh15j7/fulltext.pdf
 | language = en
 | date = Nov 15, 1974
 }}{{Dead link|date=2020年2月 |bot=InternetArchiveBot |fix-attempted=yes }}</ref>
}}
'''d<sup>4</sup>sp杂化'''（{{lang-en|d<sup>4</sup>sp hybridization}}）是指一个[[原子]]内的四个''n-1''[[d轨道]]、一个''n''[[s轨道]]和一个''n''[[p轨道]]发生[[轨道杂化|杂化]]的过程。原子发生d<sup>4</sup>sp杂化后，上述''n-1''d轨道、''n''s轨道和''n''p轨道便会转化成为六个[[杂化轨道]]，称为“[[d4sp杂化轨道|d<sup>4</sup>sp杂化轨道]]”。六个d<sup>4</sup>sp杂化轨道对称地分布于水平面两侧，每侧的三个轨道的[[对称轴]]呈正[[三棱锥形]]，整体空间构型为正[[三棱柱]]。<ref>{{cite web| title =价键理论的主要内容：配位数与配离子的空间构型| work =配合物的化学键理论| accessdate =2012-01-31| url =http://202.116.45.198/wjhx/wjhx03/yuli/chap10/sect_2/know_2.html| language =zh| deadurl =yes| archiveurl =https://web.archive.org/web/20160304113005/http://202.116.45.198/wjhx/wjhx03/yuli/chap10/sect_2/know_2.html| archivedate =2016-03-04}}</ref>杂化过程中，[[能量]]相近的d轨道、s轨道和p轨道发生叠加，不同类型的[[原子轨道]]重新分配能量并调整方向。

== 参考文献 ==
{{reflist}}

{{軌域}}

[[category:轨道杂化]]
[[Category:軌域]]