查看“︁2-甲基十三烷”︁的源代码

{{Chembox
| Name = 
| NameEn = 2-Methyltridecane
| ImageFile = 2-Methyltridecane-2D-skeletal.svg
|  ImageSize = 
|  ImageAlt = 
| IUPACName = 
| IUPACNameZh = 
| OtherNames = 
| Section1 = {{Chembox Identifiers
|   CASNo = 1560-96-9
|   CASNo_Ref = {{cascite|correct|CAS}}
|   PubChem = 15269
|   UNII = 6UNR6OUH0J
|   ChemSpiderID = 14534
|   ChEBI = 84277
|   StdInChI=1S/C14H30/c1-4-5-6-7-8-9-10-11-12-13-14(2)3/h14H,4-13H2,1-3H3
|   StdInChIKey = CJBFZKZYIPBBTO-UHFFFAOYSA-N
|   SMILES = CC(C)CCCCCCCCCCC }}
| Section2 = {{Chembox Properties
| C=14 | H=30
|   Appearance = 
|   Density = 
|   MeltingPt = {{convert|-21|C|K}}<ref>Petrov, A. D. Synthesis and properties of branched C12-C24 paraffins. ''Doklady - Akademiya Nauk Azerbaidzhanskoi SSR'', 1955. 11 (11): 747-755. ISSN: 0002-3078.</ref>
|   BoilingPt = {{convert|121.5|C|K}}（12 Torr）<ref>Petrov, Al. A.; Sergienko, S. R.; Nechitailo, N. A.; Tsedilina, A. L. Synthesis and properties of monomethyl alkanes of composition C12-16. ''Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya'', 1959. 1091-1097. ISSN: 0002-3353.</ref>
|   Solubility =  }}
| Section3 = {{Chembox Hazards
|   MainHazards = 
|   FlashPt = 
|   Autoignition =  }}
}}
'''2-甲基十三烷'''是一种[[有机化合物]]，化学式为[[C14H30|<chem>C14H30</chem>]]，它是[[十四烷]]的同分异构体之一。它可由2,2-二甲基-3-癸基环硫乙烷的还原反应制备。<ref>{{cite journal|journal=Tetrahedron Letters|volume=24|issue=15|language=en|date=1983|pages=1657–1660|doi=10.1016/S0040-4039(00)81737-2|url=https://linkinghub.elsevier.com/retrieve/pii/S0040403900817372|title=Reduction of thiiranes to alkenes and alkanes|accessdate=2020-06-10|author=J.R. Schauder, J.N. Denis, A. Krief|archive-date=2018-06-09|archive-url=https://web.archive.org/web/20180609040920/https://linkinghub.elsevier.com/retrieve/pii/S0040403900817372|dead-url=no}}</ref>金属[[镧]]在[[四氢呋喃]]中还原2-碘代-2-甲基十三烷，可以得到2-甲基十三烷，副产物包括12,12,13,13-四甲基二十四烷及一些[[烯烃]]产物。<ref>{{cite journal|journal=The Journal of Organic Chemistry|volume=67|issue=3|language=en|issn=0022-3263|date=2002-02|pages=966–969|doi=10.1021/jo016205n|url=https://pubs.acs.org/doi/10.1021/jo016205n|title=Reduction of Organic Halides with Lanthanum Metal: A Novel Generation Method of Alkyl Radicals|accessdate=2020-06-10|author=Toshiki Nishino, Toshihisa Watanabe, Mitsuo Okada, Yutaka Nishiyama, Noboru Sonoda|archive-date=2019-04-03|archive-url=https://web.archive.org/web/20190403161931/https://pubs.acs.org/doi/10.1021/jo016205n|dead-url=no}}</ref>雷尼镍加氢还原13-溴-2-甲基十三烷-2-醇也会得到少许的2-甲基十三烷。<ref>{{cite journal|journal=The Journal of Organic Chemistry|volume=53|issue=2|language=en|issn=0022-3263|date=1988-01|pages=432–434|doi=10.1021/jo00237a041|url=https://pubs.acs.org/doi/abs/10.1021/jo00237a041|title=Deoxygenation of tertiary alcohols using Raney nickel|accessdate=2020-06-10|author=Marie E. Krafft, William J. Crooks}}</ref>

==参考文献==
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[[Category:烷烃]]