查看“︁2,3,3-三甲基戊烷”︁的源代码
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2,3,3-三甲基戊烷
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{{Chembox | Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 477209965 | ImageFile = 2,3,3-Trimethylpentane.svg | ImageFile_Ref = {{chemboximage|correct|??}} | ImageSize = 160 | ImageName = Skeletal formula of 2,3,3-trimethylpentane with some implicit hydrogens shown | IUPACName = 2,3,3-Trimethylpentane<ref>{{Cite web|title=2,3,3-TRIMETHYLPENTANE - Compound Summary|url=https://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=11215&loc=ec_rcs|work=PubChem Compound|publisher=National Center for Biotechnology Information|accessdate=11 March 2012|location=USA|date=26 March 2005|at=Identification and Related Records|archive-date=2021-11-24|archive-url=https://web.archive.org/web/20211124142319/https://pubchem.ncbi.nlm.nih.gov/compound/11215}}</ref> |Section1={{Chembox Identifiers | CASNo = 560-21-4 | CASNo_Ref = {{cascite|correct|CAS}} | PubChem = 11215 | ChEBI = 143849 | ChemSpiderID = 10742 | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | EINECS = 209-207-2 | UNNumber = 1262 | RTECS = SA3321000 | SMILES = CCC(C)(C)C(C)C | StdInChI = 1S/C8H18/c1-6-8(4,5)7(2)3/h7H,6H2,1-5H3 | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = OKVWYBALHQFVFP-UHFFFAOYSA-N | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} }} |Section2={{Chembox Properties | C=8 | H=18 | Appearance = 无色液体 | MeltingPt = {{convert|171|-|173|K|C}} | BoilingPt = {{convert|387.5|-|388.1|K|C}} | HenryConstant = 2.4 nmol Pa<sup>−1</sup> kg<sup>−1</sup> }} |Section3={{Chembox Thermochemistry | DeltaHf = −255.1–−252.3 kJ mol<sup>−1</sup> | DeltaHc = −5.4683–−5.4657 MJ mol<sup>−1</sup> | HeatCapacity = 245.56 J K<sup>−1</sup> mol<sup>−1</sup> }} |Section4={{Chembox Hazards | GHSPictograms = {{GHS flame}} {{GHS exclamation mark}} {{GHS health hazard}} {{GHS environment}} | GHSSignalWord = '''危险''' | HPhrases = {{H-phrases|225|304|315|336|410}} | PPhrases = {{P-phrases|210|261|273|301+310|331}} | FlashPtC = −6 | AutoignitionPtC = 425 }} |Section5={{Chembox Related | OtherFunction_label = alkanes | OtherFunction = {{Unbulleted list|[[新戊烷]]|[[2,2-二甲基丁烷]]|[[2,3-二甲基丁烷]]|[[三甲基丁烷]]|[[四甲基丁烷]]|[[四乙基甲烷]]|[[2,2,4-三甲基戊烷]]|[[2,3,4-三甲基戊烷]]|[[四叔丁基甲烷]]|[[2,3-二甲基己烷]]|[[2,5-二甲基己烷]]}} }} }} '''2,3,3-三甲基戊烷'''是[[辛烷]]的同分异构体之一,化学式为<chem>C8H18</chem>。它可由[[乙烯]]和[[2,3-二甲基丁烷]]在十钨酸四丁基铵<!-- CAS 68109-03-5 -->的催化下反应得到。<ref>{{cite journal|journal=Journal of the American Chemical Society|volume=115|issue=25|language=en|issn=0002-7863|date=1993-12|pages=12212–12213|doi=10.1021/ja00078a089|url=https://pubs.acs.org/doi/abs/10.1021/ja00078a089|title=Selective ethylation and vinylation of alkanes via polyoxotungstate photocatalyzed radical addition reactions|accessdate=2020-06-19|author=B. Scott Jaynes, Craig L. Hill}}</ref>它在高温下可以分解。<ref>{{cite journal|journal=International Journal of Chemical Kinetics|volume=1|issue=2|language=en|issn=0538-8066|date=1969-03|pages=245–278|doi=10.1002/kin.550010209|url=http://doi.wiley.com/10.1002/kin.550010209|title=Thermal decomposition of 3,4-dimethylpentene-1, 2,3,3-trimethylpentane, 3,3-dimethylpentane, and isobutylbenzene in a single pulse shock tube|accessdate=2020-06-19|author=Wing Tsang}}</ref>它的性质和[[2,2,3-三甲基戊烷]]相似,它们之间难以分离。<ref>{{cite journal|journal=Journal of the American Chemical Society|volume=55|issue=6|language=en|issn=0002-7863|date=1933-06|pages=2607–2608|doi=10.1021/ja01333a509|url=https://pubs.acs.org/doi/abs/10.1021/ja01333a509|title=THE TRIMETHYLPENTANES|accessdate=2020-06-19|author=K. C. Laughlin, Frank C. Whitmore}}</ref> ==参考文献== {{reflist}} {{hydrocarbon-stub}} [[Category:辛烷]]
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