查看“︁高锝酸铷”︁的源代码

{{NoteTA
|G1 = Chemistry
}}
{{Chembox
|ImageFile=K2ReO4.png
|Section3={{Chembox Structure
| CrystalStruct= [[四方晶系]]
| SpaceGroup= I41/a
| LattConst_a= 576.2&nbsp;pm
|LattConst_c= 1354.3&nbsp;pm
}}
|Section1={{Chembox Identifiers
| CASNo= 13597-49-4
| CASNo_Ref = {{cascite|correct|CAS}}
|SMILES=[Rb+].[O-][Tc](=O)(=O)=O
}}
|Section2={{Chembox Properties
| Appearance=白色固体<ref name="Technetium: Chemistry and Radiopharmaceutical Applications" />
|Rb=1|Tc=1|O=4
| Density= 
| MeltingPt= 
| BoilingPt= 
| Solubility= 1.167&nbsp;g/100mL<ref name="Technetium: Chemistry and Radiopharmaceutical Applications">{{cite book|author=Klaus Schwochau|title=Technetium: Chemistry and Radiopharmaceutical Applications|publisher=John Wiley & Sons|date=2008-11|page=129|ISBN=3527613374}}</ref>}}
|Section8={{Chembox Related
|OtherAnions=[[高氯酸铷]]<br />[[高锰酸铷]]
|OtherCations=[[高锝酸]]<br />[[高锝酸锂]]<br />[[高锝酸钠]]<br />[[高锝酸钾]]<br />[[高锝酸铯]]
}}
}}

'''高锝酸铷'''是[[铷]]的[[高锝酸盐]]，化学式 RbTcO<sub>4</sub>。

== 制备 ==
高锝酸铷可以由[[碳酸铷]]和[[高锝酸铵]]反应而成。<ref name="Chemical Trends in Solid Alkali Pertechnetates">{{cite book|author=Jamie Weaver, Chuck Z. Soderquist, Nancy M. Washton, Andrew S. Lipton, Paul L. Gassman, Wayne W. Lukens, Albert A. Kruger, Nathalie A. Wall, John S. McCloy|title=Chemical Trends in Solid Alkali Pertechnetates|publisher=Inorg. Chem.|date=2017-02|pages=2533-2544|DOI=10.1021/acs.inorgchem.6b02694}}</ref>

<chem>Rb2CO3 + 2 NH4TcO4 -> 2 RbTcO4 + (NH4)2CO3</chem>

== 性质==
高锝酸铷的[[晶体结构]]是[[四方晶系]]，[[空间群]] I41/a，[[晶格参数]] a&nbsp;= 576.2&nbsp;[[皮米|pm]] 和c&nbsp;= 1354.3&nbsp;pm。高锝酸根中，Tc–O键长为 172.3&nbsp;pm，O–Tc–O键角为 108.34°。<ref name="Chemical Trends in Solid Alkali Pertechnetates" />

== 参考资料==
<references />
{{铷化合物}}
{{锝化合物}}

[[Category:铷化合物]]
[[Category:高锝酸盐]]
{{inorganic-compound-stub}}