查看“︁高铼酸钡”︁的源代码

{{NoteTA
|G1 = Chemistry
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{{chembox
| verifiedrevid = 
|   Name = 高铼酸钡
|   ImageFile = barium perrhenate.png
|   ImageName = 
|   OtherNames = 偏高铼酸钡
|   IUPACName = 
| Section1 = {{Chembox Identifiers
| CASNo = 13768-52-0
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|  StdInChI  = 
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| Section2 = {{Chembox Properties
|   Formula = Ba(ReO<sub>4</sub>)<sub>2</sub>
|   MolarMass = 637.74
|   Appearance = 无色或白色固体
|   Density = 5.91；4.216g/cm<sup>3</sup>（四水）
|   MeltingPt = 
|   BoilingPt = 
|   Solubility = {{nowrap|1.52<sup>0</sup>；8.13<sup>30</sup>；21.51<sup>50</sup>（水）}}<BR>0.372<sup>20</sup>（甲醇）<BR>0.24<sup>18.5</sup>（乙醇）
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| Section8 = {{Chembox Related
|   Function = 
|   OtherFunctn = 
|   OtherAnions = [[高锰酸钡]]<br />[[高锝酸钡]]
|   OtherCations = [[高铼酸钙]]<br />[[高铼酸锶]]
|   OtherCpds = [[氢氧化钡]]<br />[[高铼酸]]
  }}
}}

'''高铼酸钡'''是一种无机化合物，化学式为Ba(ReO<sub>4</sub>)<sub>2</sub>。

==制备==
高铼酸钡可由[[高铼酸]]和[[氢氧化钡]]在水中反应得到：
::<math>\mathsf{ 2 HReO_4 + Ba(OH)_2 \ \xrightarrow{}\ Ba(ReO_4)_2 + 2 H_2O }</math>

==物理性质==
高铼酸钡是白色固体，可溶于水，其溶解度随着温度的升高而升高。微溶于[[乙醇]]和[[甲醇]]。

它从溶液中可以析出二水合物
<ref>{{книга
 | автор         = J. G. F. Druce
 | заглавие      = Rhenium
 | ссылка        = https://books.google.com.ua/books?id=SegaAgAAQBAJ&pg=PA42&lpg=PA42&dq=%22Ba(ReO4)2%22+Rhenium&source=bl&ots=kyOcVFb0DL&sig=94vGOrguUrvJRBis6XsdefbU9OU&hl=ru&sa=X&ei=6tiGVfH2I6afyAPTg4KwBw&redir_esc=y#v=onepage&q=%22Ba(ReO4)2%22%20Rhenium&f=false
 | место         = 
 | издательство  = Cambridge University Press
 | год           = 2013
 | том           = 
 | страниц       = 102
 | страницы      = 
 | isbn          = 978-1-107-69324-1
 | ref           = 
}}</ref>
和四水合物
<ref>J. Macíček, T. Todorov Structure of a barium perrhenate tetrahydrate. Acta Crystallographica Section C, 1992. 48(4) pp. 599-603. DOI:10.1107/S0108270191011125.</ref>，它们在真空中加热至120℃失水。
<ref>{{книга
 | автор         =  Georg Brauer
 | заглавие      = Handbook of Preparative Inorganic Chemistry
 | ссылка        = https://books.google.com.ua/books?id=Pef47TK5NfkC&pg=PA1485&lpg=PA1485&dq=%22Ba(ReO4)2%22+Rhenium&source=bl&ots=W7JHhezgUJ&sig=akkf4QWxaxl9cxY7Ay70oQMBGjo&hl=ru&sa=X&ei=6tiGVfH2I6afyAPTg4KwBw&redir_esc=y#v=onepage&q=%22Ba(ReO4)2%22%20Rhenium&f=false
 | ответственный = 
 | место         = 
 | издательство  = Elsevier
 | год           = 2012
 | том           = 2
 | страниц       = 882
 | страницы      = 
 | isbn          = 
 | ref           = 
}}</ref>.

Ba(ReO{{sub|4}}){{sub|2}}·4H{{sub|2}}O晶体属[[单斜晶系]]，空间群为'''''P 2{{sub|1}}/n'''''，晶胞参数为''a'' = 0,7376nm, ''b'' = 1,2452nm, ''c'' = 1,2173nm, β = 90,04°, Z = 4。
==参考文献==
{{reflist}}
==参见==
*Руководство по неорганическому синтезу: В 6-ти т. / Ред. Брауэр Г.. — М.: Мир, 1985. 5: 360.
*R. D. W. Kemmitt, R. D. Peacock. The Chemistry of Manganese, Technetium and Rhenium. Elsevier, 2013: 223. ISBN 0-08-018870-2.
*SK Majumdar, RA Pacer, CL Rulfs. [https://deepblue.lib.umich.edu/bitstream/handle/2027.42/33043/0000429.pdf?sequence=1 Rhenium and technetium (VI) and meso-(VII) species] {{Wayback|url=https://deepblue.lib.umich.edu/bitstream/handle/2027.42/33043/0000429.pdf?sequence=1 |date=20170818153007 }}. Journal of Inorganic & Nuclear Chemistry, 1969 , 31 (1): 33-41

{{钡化合物}}
{{高铼酸盐}}

[[category:钡化合物]]
[[category:高铼酸盐]]
[[Category:缺少物质图片的化学品条目]]