查看“︁高铼酸钠”︁的源代码

{{NoteTA
|G1 = Chemistry
}}
{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 311320281
| ImageFile = NaReO4tetra.png
| ImageFile1 = NaReO4.JPG
| IUPACName = 
| OtherNames = 
| Section1 = {{Chembox Identifiers
|   CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 13472-33-8 
|   PubChem = 5107658
|   RTECS = WD3675000
| ChEMBL_Ref = {{ebicite|changed|EBI}}
| ChEMBL = 444819
|   InChI = 1S/Na.4O.Re/q+1;;;;-1;
|   SMILES = [O-][Re](=O)(=O)=O.[Na+]
  }}
| Section2 = {{Chembox Properties
|   Formula = NaReO<sub>4</sub>
|   MolarMass = 273.194
|   Appearance = 白色粉末状晶体
|   Density = 5.39 g/cm<sup>3</sup>
|   MeltingPt = 
|   BoilingPt = 
|   Solubility = 103.3 g/100 mL (0 °C)<br>145.3 g/100 mL (30 °C)<br>173.0 g/100 mL (50 °C)
  }}
| Section3 = {{Chembox Hazards
|   MainHazards = 氧化剂
|   FlashPt = 不可燃
|   Autoignition = 
  }}
}}
'''高铼酸钠'''是一种无机化合物，化学式为NaReO<sub>4</sub>。这是一种白色粉末状晶体，具有吸湿性<ref>{{Cite web|url=http://www.basechem.org/chemical/16520|title=高铼酸钾|accessdate=2017-04-06|author=|date=|publisher=化学品数据库|archive-date=2017-04-06|archive-url=https://web.archive.org/web/20170406201333/http://www.basechem.org/chemical/16520|dead-url=no}}</ref>，通常用作制备其他[[铼]]化合物的前体。其化學結構和[[過氯酸鈉]]、[[過錳酸鈉]]的結構相似。

== 製備 ==
過錸酸鈉可由[[七氧化二铼]]和氫氧化鈉反應，或由其對應鉀鹽，過錸酸鉀，行陽離子交換得到。<ref name="APG">{{Cite book|chapter=Nonahydridorhenate Salts|authors=A. P. Ginsberg, C. R. Sprinkle|title=Inorganic Syntheses|year=1972|volume=13|pages=219–225|doi=10.1002/9780470132449.ch45|series=Inorganic Syntheses|isbn=9780470132449}}</ref>

過錸酸鈉也可由在鹼(氫氧化鈉)存在的條件下，由[[錸]]金屬和過氧化氫混合製得：<ref name="MH">{{Cite journal|title=Improved Synthesis of Carbonylrhenium|first1=Lisa S.|last2=Gould|first2=George L.|journal=Journal of Organometallic Chemistry|issue=2|doi=10.1016/s0022-328x(00)99461-0|year=1988|volume=342|pages=243–244|last3=Heinekey|first3=D. Michael|last1=Crocker}}</ref>

<chem>2 Re + 7 H2O2 + 2 NaOH -> 2 NaReO4 + 8 H2O</chem>

== 反應 ==
過錸酸鈉可在乙醇中和鈉反應獲取九氫合錸(VII)酸鹽。<ref name="APG" />

過錸酸鈉也被作為合成錸的氮化物(如Re<sub>3</sub>N, Re<sub>2</sub>N, Re<sub>3</sub>N<sub>2</sub>, ReN<sub>2</sub>, ReN<sub>3</sub>, ReN<sub>4</sub>)的前體，其可用於作為氨合成和[[加氫脫氮]]的催化劑。<ref>{{Cite journal|title=Rhenium Metal and Rhenium Nitride Thin Films Grown by Atomic Layer Deposition|first1=Jani|last2=Mizohata|first2=Kenichiro|date=2018-08-27|journal=Angewandte Chemie International Edition|issue=44|doi=10.1002/anie.201806985|volume=57|pages=14538–14542|language=en|issn=1433-7851|pmid=30048031|last3=Meinander|first3=Kristoffer|last4=Mattinen|first4=Miika|last5=Vehkamäki|first5=Marko|last6=Räisänen|first6=Jyrki|last7=Ritala|first7=Mikko|last8=Leskelä|first8=Markku|last1=Hämäläinen|hdl=10138/325623|hdl-access=free}}</ref>

過錸酸鈉也可用於合成[[十羰基二錸]]。<ref name="MH" />

== 扩展阅读 ==
{{refbegin}}
*{{cite journal|title=The Thermodynamic Properties of High Temperature Aqueous Solutions. II. Standard Partial Molal Heat Capacities of Sodium Perrhenate and Perrhenic Acid from 0 to 100o|last=Ahluwalia|first=J. C.|date=1 December 1964|journal=Journal of the American Chemical Society|issue=24|doi=10.1021/ja01078a001|volume=86|pages=5377–5381|coauthors=Cobble, J. W.}}
*{{cite journal|title=Nuclear magnetic resonance of aqueous solutions of sodium perrhenate|last=Dwek|first=Raymond A.|date=1 May 1970|journal=The Journal of Physical Chemistry|issue=10|doi=10.1021/j100909a038|volume=74|pages=2232–2233|coauthors=Luz, Z.; Shporer, M.}}
{{refend}}

== 參考資料 ==
{{Reflist}}

{{钠化合物}}
{{高铼酸盐}}
[[Category:钠化合物]]
[[Category:高铼酸盐]]