查看“︁高氯酸钕”︁的源代码

{{NoteTA
|G1=化学
}}
{{Chembox
| Name = 高氯酸钕
| NameEn = neodymium perchlorate
| ImageFile = Neodymium(III) perchlorate.svg
| ImageName = 高氯酸钕的结构
|Section1={{Chembox Identifiers
| InChI = InChI=1S/3ClHO4.Nd/c3*2-1(3,4)5;/h3*(H,2,3,4,5);/q;;;+3/p-3<ref name="chemspider"/>
| InChIKey = HBKMAYJLXKBOER-UHFFFAOYSA-K<ref name="chemspider"/>
| CASNo = 13498-06-1
| CASNo_Ref = {{cascite|correct|chemicalbook}}<ref name="chemicalbook"/>
| PubChem = 13783607
| ChemSpiderID = 21160135
| SMILES = [O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Nd+3]<ref name="chemspider"/>
| EC-number = 236-821-8
| UNNumber = 3098<ref name="chemicalbook"/>
}}
|Section2={{Chembox Properties
| Formula = Nd(ClO<sub>4</sub>)<sub>3</sub>
| MolarMass = 442.594<ref name="chemspider"/>
| DensitySolid = 1.436<ref name="chemicalbook"/>
| VaporPressure = 0.12（20°C）<ref name="chemicalbook"/>
| Appearance = 浅紫色晶体（无水）<ref>Grupe, Sven; Wickleder, Mathias S. The UCl<sub>3</sub> type of structure with complex anions and its addition-substitution variant. Syntheses and crystal structure of Nd(ClO<sub>4</sub>)<sub>3</sub> and Na<sub>0.75</sub>Nd<sub>0.75</sub>(ReO<sub>4</sub>)<sub>3</sub>. ''Zeitschrift fuer Anorganische und Allgemeine Chemie'', 2003. 629 (6): 955-958. ISSN: 0044-2313.</ref>
}}
|Section7={{Chembox Hazards
| EUHazardSymbol = {{Chembox EUHazardSymbol|O|C}}<ref name="chemicalbook"/>
| RPhrases = {{R8}}，{{R34}}<ref name="chemicalbook"/>
| SPhrases = {{S17}}，{{S26}}，{{S27}}，{{S36/37/39}}，{{S45}}<ref name="chemicalbook"/>
}}
}}

'''高氯酸钕'''（{{lang-en|neodymium perchlorate}}）是[[钕]]的[[高氯酸]]盐，分子式为Nd(ClO<sub>4</sub>)<sub>3</sub>。

== 制备 ==
将[[氧化钕]]溶于[[高氯酸]]溶液中可得到高氯酸钕:
:<math>\rm Nd_2O_3+6HClO_4 \rightarrow 2Nd(ClO_4)_3+3H_2O</math><ref name="gu'ansuan"/>

== 化学性质 ==
高氯酸钕能与[[甘氨酸]]和[[丙氨酸]]形成[[配合物]]，其化学式为Nd<sub>2</sub>([[甘氨酸|Gly]])<sub>5</sub>([[丙氨酸|Ala]])<sub>3</sub>(ClO<sub>4</sub>)<sub>6</sub>·2H<sub>2</sub>O<ref name="gan'ansuanbing'ansuan"/>。高氯酸钕也能和[[谷氨酸]]配合<ref name="gu'ansuan"/>。

== 参考资料 ==
{{reflist|refs=
<ref name="chemicalbook">{{CB|1721250|高氯酸钕(III) {{!}} 13498-06-1|2017-09-23}}</ref>

<ref name="chemspider">{{CS|21160135|Neodymium triperchlorate {{!}} Cl3NdO12 {{!}} ChemSpider|2017-09-23}}</ref>

<ref name="gan'ansuanbing'ansuan">{{Cite journal
|author=陈平初
|coauthors=詹彤;刘宛乔;詹正坤;屈松生
|title=高氯酸钕和甘氨酸及丙氨酸混配型配合物的热化学研究
|url=http://www.ixueshu.com/document/b2e37797d990fac0318947a18e7f9386.html
|journal=《武汉大学学报（理学版）》
|year=2002
|volume=48
|issue=6
|pages=663－666
|access-date=2017-09-23
|archive-date=2019-12-02
|archive-url=https://web.archive.org/web/20191202135249/https://www.ixueshu.com/document/b2e37797d990fac0318947a18e7f9386.html
|dead-url=no
}}</ref>

<ref name="gu'ansuan">{{Cite journal
|author=吴新明
|coauthors=张忠海;刘义;屈松生
|title=高氯酸钕与L-谷氨酸配合物单晶体的标准生成焓及热化学研究
|url=http://www.ixueshu.com/document/047267c4bb3686d5318947a18e7f9386.html
|journal=《武汉大学学报（理学版）》
|year=2001
|volume=47
|issue=4
|pages=407－410
|access-date=2017-09-23
|archive-date=2019-11-29
|archive-url=https://web.archive.org/web/20191129131313/https://www.ixueshu.com/document/047267c4bb3686d5318947a18e7f9386.html
|dead-url=no
}}</ref>
}}

{{钕化合物}}
{{高氯酸盐}}

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[[Category:钕化合物]]
[[Category:高氯酸盐]]
[[Category:缺少物质图片的化学品条目]]