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過氧化銅
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{{chembox | Watchedfields = | verifiedrevid = | Name = |CustomizedImage=[[File:Cu2+.svg]][[File:Peroxide anion.svg|96px]] | IUPACName = | OtherNames = 二氧化銅 |Section1={{Chembox Identifiers | ChemSpiderID_Ref = | ChemSpiderID = | UNII_Ref = | UNII = | InChI = | SMILES = [Cu+2].[O-]-[O-] | InChIKey = | InChI1 = | InChIKey1 = | SMILES1 = | StdInChI_Ref = | StdInChI = | StdInChIKey_Ref = | StdInChIKey = | CASNo = 12019-06-6 | CASNo_Ref = {{cascite|correct|CAS}} | PubChem = | RTECS = | EINECS = | KEGG_Ref = | KEGG = }} |Section2={{Chembox Properties | Formula = CuO<sub>2</sub> | MolarMass = 95.945 | Appearance = 暗橄欖綠晶體 | Density = | Solubility = 不溶 | SolubleOther = 不溶 | Solvent = [[乙醇]] | MeltingPtC = | BoilingPtC = | BandGap = }} |Section3={{Chembox Structure | Coordination = | CrystalStruct = }} |Section4={{Chembox Thermochemistry | DeltaHf = | Entropy = }} |Section7={{Chembox Hazards | ExternalSDS = | EUClass = | NFPA-H = | NFPA-F = | NFPA-R = | RPhrases = | SPhrases = | PEL = | REL = | IDLH = }} |Section8={{Chembox Related | OtherAnions = | OtherCations = }} }} '''過氧化銅'''是一種[[無機化合物]],分子式CuO<sub>2</sub>。 == 性質 == 其為[[銅]]的[[過氧化物]],為暗橄欖綠色晶體或懸浮物。不溶於水或乙醇,但與一個水分子組成[[結晶水合物]]。在潮濕狀態下容易分解,<ref name=EW>{{cite book|title=Electrical World, Volume 39|date=1902|page=997|url=https://books.google.com/books?id=OU9EAQAAIAAJ&pg=PA997&dq=%22copper+peroxide%22&hl=en&sa=X&ved=0CDcQ6AEwBWoVChMIlOnU0vz-yAIVRKseCh2a2Q7P#v=onepage&q=%22copper%20peroxide%22&f=false|access-date=2019-11-19|archive-date=2020-07-29|archive-url=https://web.archive.org/web/20200729170338/https://books.google.com/books?id=OU9EAQAAIAAJ&pg=PA997&dq=%22copper+peroxide%22&hl=en&sa=X&ved=0CDcQ6AEwBWoVChMIlOnU0vz-yAIVRKseCh2a2Q7P#v=onepage&q=%22copper%20peroxide%22&f=false}}</ref>除非保存於6℃以下。在乾燥環境下則更為穩定。<ref name=CSL>{{cite book|title=Journal of the Chemical Society of London, Volume 48, Part 1|date=1885|location=London|page=124|url=https://books.google.com/books?id=Y0gxAAAAYAAJ&pg=PA124&dq=%22copper+peroxide%22&hl=en&sa=X&ved=0CCkQ6AEwA2oVChMIlOnU0vz-yAIVRKseCh2a2Q7P#v=onepage&q=%22copper%20peroxide%22&f=false|access-date=2019-11-19|archive-date=2020-07-29|archive-url=https://web.archive.org/web/20200729162131/https://books.google.com/books?id=Y0gxAAAAYAAJ&pg=PA124&dq=%22copper+peroxide%22&hl=en&sa=X&ved=0CCkQ6AEwA2oVChMIlOnU0vz-yAIVRKseCh2a2Q7P#v=onepage&q=%22copper%20peroxide%22&f=false}}</ref> == 制备 == 它由稀釋的[[氨]]及[[氫氧化銅]]製備的施魏策爾試劑,在低溫下與[[過氧化氫]]溶液所得,<ref name=RS2>{{cite book|title=The collected works of Sir Humphry Davy: Discourses delivered before the Royal society. Elements of agricultural chemistry, pt. I|date=1894|publisher=The Chemical Society (Great Britain)|page=32|url=https://books.google.com/books?id=ELtLAAAAYAAJ&pg=PA32&dq=%22copper+peroxide%22&hl=en&sa=X&ved=0CC8Q6AEwBGoVChMIlOnU0vz-yAIVRKseCh2a2Q7P#v=onepage&q=%22copper%20peroxide%22&f=false|access-date=2019-11-19|archive-date=2020-07-29|archive-url=https://web.archive.org/web/20200729162543/https://books.google.com/books?id=ELtLAAAAYAAJ&pg=PA32&dq=%22copper+peroxide%22&hl=en&sa=X&ved=0CC8Q6AEwBGoVChMIlOnU0vz-yAIVRKseCh2a2Q7P#v=onepage&q=%22copper%20peroxide%22&f=false}}</ref>而當中氨的份量必不可過多。{{r|RS2}} 它亦可用冰點的過氧化氫溶液與氫氧化銅的懸浮物反應所得:<ref name=IC1>{{cite book|last1=Friend|first1=John Newton|title=A Text-book of Inorganic Chemistry|url=https://archive.org/details/textbookofinorgav11p2frie|date=1924|publisher=C. Griffin, Ltd|page=[https://archive.org/details/textbookofinorgav11p2frie/page/276 276]}}</ref> :<math>\mathsf{ Cu(OH)_2 + H_2O_2 \ \xrightarrow{0^oC}\ CuO_2\cdot H_2O\downarrow + H_2O }</math> 另一個方法是由[[氧化銅]]的細粉末與低溫的過氧化氫反應,但此過程十分緩慢。{{r|CSL}} == 參考文献 == {{reflist}} == 拓展阅读 == <small> * {{cite journal|journal=J. Chem. Soc., Trans.|volume=121|issue=0|language=en|issn=0368-1645|date=1922|pages=238–243|doi=10.1039/CT9222100238|url=http://xlink.rsc.org/?DOI=CT9222100238|title=XXVIII.—The peroxidic compounds of copper|accessdate=2019-11-19|author=Joan Aldridge, Malcolm Percival Applebey}} </small> {{铜化合物}} {{多氧化物}} [[Category:二价铜化合物]] [[Category:過氧化物]]
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