查看“︁苯基三氯化锗”︁的源代码

{{Chembox
|ImageFile=Trichlorophenylgermane.svg
|Section1={{Chembox Identifiers
| CASNo= 1074-29-9
| CASNo_Ref = {{cascite|correct|CAS}}
| EC-number= 214-039-8
| PubChem         = 66176
|SMILES=c1ccccc1[Ge](Cl)(Cl)Cl
}}
|Section2={{Chembox Properties
| Appearance= 无色液体<ref name="Sigma" />
|C=6|H=5|Ge=1|Cl=3
| Density= 1.584 g·cm<sup>−3</sup> (25 °C)<ref name="Sigma" />
| BoilingPt= 105–106 °C（12 mmHg）<ref name="Sigma">{{Sigma-Aldrich|Aldrich|id=288195|Name=Phenylgermanium trichloride, 98%|Abruf=2015-11-03}}</ref>
}}
}}

'''苯基三氯化锗'''是一种[[有机锗化合物]]，化学式 C<sub>6</sub>H<sub>5</sub>GeCl<sub>3</sub>。

== 制备 ==
苯基三氯化锗可以由[[四氯化锗]]和[[格氏试剂]][[苯基溴化镁]]或是[[四苯基锗]]在350 °C下反应而成。它也可以由[[碘苯]]和[[三氯锗基铯]]反应而成。<ref name="Richard W. Weiss">{{cite book | last=Weiss | first=Richard | title=Compounds of germanium, tin, and lead, including biological activity and commercial application : covering the literature from 1937 to 1964 | url=https://archive.org/details/compoundsgermani1964weis | publisher=Springer Science+Business Media | publication-place=Berlin New York | year=1967 | isbn=978-3-642-51889-8 | oclc=864236481|page=[https://archive.org/details/compoundsgermani1964weis/page/n101 85]}}</ref>
:<math>\mathrm{2 BrMgC_6H_5 + 2 GeCl_4 \longrightarrow 2 Ge(C_6H_5)Cl_3 + \ MgBr_2 + \ MgCl_2}</math>
:<math>\mathrm{Ge(C_6H_5)_4 + \ 3 \ GeCl_4 \longrightarrow 4 \ Ge(C_6H_5)Cl_3 }</math>
:<math>\mathrm{I{-}C_6H_5 + CsGeCl_3 \longrightarrow Ge(C_6H_5)Cl_3 + \ CsI}</math>

== 性质==
苯基三氯化锗是闪点 113&nbsp;°C的无色液体。<ref name="Sigma" />

== 反应==
它和[[四苯基锗]]在[[三氯化铝]]存在下反应，生成[[二苯基二氯化锗]]。<ref name="Jane E. Macintyre">{{cite book | title=Dictionary of organometallic compounds | url=https://archive.org/details/dictionaryoforga0001unse_x8u1 | publisher=Chapman and Hall | publication-place=London New York | year=1995 | isbn=978-0-412-43060-2 | oclc=31763519 | ref={{sfnref | Chapman and Hall | 1995}}|page=1733}}</ref>

== 参考资料==
<references />
{{锗化合物}}

[[Category:有机锗化合物]]
[[Category:锗-氯化合物]]