查看“︁臭氧化钠”︁的源代码

{{Chembox
<!-- Images -->
| ImageFile      = Sodium ozonide.png
| ImageSize      = 
| ImageAlt       = 
<!-- Names -->
| IUPACName      = Sodium ozonide
| OtherNames     = 
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| Section1       = {{Chembox Identifiers
| CASNo          = 
| PubChem        = 
| SMILES         = [Na+].[O-]O[O]
| StdInChI=1S/Na.HO3/c;1-3-2/h;1H/q+1;/p-1
| StdInChIKey=ZWXLQJCNVRJOAA-UHFFFAOYSA-M
  }}
| Section2       = {{Chembox Properties
| Formula        = NaO<sub>3</sub>
| MolarMass      = 
| Appearance     = 鲜红色固体<ref name=Klein/>
| Density        = 
| MeltingPt      = 
| BoilingPt      = 
| Solubility     = 
  }}
| Section3       = {{Chembox Hazards
| MainHazards    = 
| FlashPt        = 
| AutoignitionPt = 
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| Section4 = {{Chembox Structure
| Reference =<ref name=Klein>{{cite journal | last=Klein | first=Wilhelm | last2=Armbruster | first2=Klaus | last3=Jansen | first3=Martin | title=Synthesis and crystal structure determination of sodium ozonide | journal=Chemical Communications | publisher=Royal Society of Chemistry (RSC) | issue=6 | year=1998 | issn=1359-7345 | doi=10.1039/a708570b | pages=707–708}}</ref>
| CrystalStruct = [[亚硝酸钠]]结构（正交晶系）
| SpaceGroup = Im2m (No. 44)
| PointGroup = 
| LattConst_a = 3.5070 Å
| LattConst_b = 5.7703 Å
| LattConst_c = 5.2701 Å
| LattConst_alpha = 
| LattConst_beta = 
| LattConst_gamma = 
| LattConst_ref =
| LattConst_Comment = 
| UnitCellVolume = 106.777 Å<sup>3</sup>
| UnitCellFormulas = 2
| Coordination = 
| MolShape = 
| OrbitalHybridisation = 
| Dipole = 
  }}
| Section8       = {{Chembox Related
| OtherAnions =  [[氧化钠]] <br> [[过氧化钠]] <br> [[超氧化钠]]
| OtherCations = [[臭氧酸]] <br> [[臭氧化锂]] <br> [[臭氧化钾]] <br> [[臭氧化铷]]<br>[[臭氧化铯]]
| OtherCpds = 
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'''臭氧化钠'''，化学式 NaO<sub>3</sub>，是[[钠]]的[[臭氧化物]]，含有臭氧根离子 (O<sub>3</sub><sup>-</sup>)。

一些实验报告声称，通过臭氧和[[氢氧化钠]]的反应，可以产生臭氧化钠，<ref>{{cite journal | last=McLachlan | first=A. D. | last2=Symons | first2=M. C. R. | last3=Townsend | first3=M. G. | title=193. Unstable intermediates. Part V. Ozonides and superoxides | journal=Journal of the Chemical Society (Resumed) | publisher=Royal Society of Chemistry (RSC) | year=1959 | issn=0368-1769 | doi=10.1039/jr9590000952 | page=952}}</ref>但产生的物质不纯，并且这种物质在室温下的稳定性与其他报告相矛盾。<ref>{{cite journal | last=Solomon | first=I. J. | last2=Kacmarek | first2=A. J. | title=Sodium Ozonide | journal=The Journal of Physical Chemistry | publisher=American Chemical Society (ACS) | volume=64 | issue=1 | year=1960 | issn=0022-3654 | doi=10.1021/j100830a507 | pages=168–169}}</ref>臭氧化钠和[[臭氧化钾]]、[[臭氧化铷]]和[[臭氧化铯]]不同，不能由金属和臭氧直接反应而成。它是在[[氨]]溶液中使用[[离子交换]]和[[穴醚]]制成的。<ref name=Klein/><ref>{{cite journal | last=Korber | first=Nikolaus | last2=Jansen | first2=Martin | title=Synthesewege zu neuen ionischen Ozoniden | journal=Chemische Berichte | publisher=Wiley | volume=125 | issue=6 | year=1992 | issn=0009-2940 | doi=10.1002/cber.19921250613 | pages=1383–1388 | language=de|trans-title=Synthetic Routes to New Ionic Ozonides}}</ref>

它在室温下不稳定，-10°C 以上时分解成[[超氧化钠]]和[[氧气]]。<ref>{{cite journal | last=Tokareva | first=S. A. | last2=Pilipenko | first2=G. P. | title=Thermal decomposition of sodium ozonide | journal=Bulletin of the Academy of Sciences, USSR Division of Chemical Science | publisher=Springer Science and Business Media LLC | volume=13 | issue=4 | year=1964 | issn=0568-5230 | doi=10.1007/bf00845322 | pages=686–688}}</ref>

:<chem>2NaO3 -> 2NaO2 + O2</chem>

不过，臭氧化钠可以在 -18°C下存放几个月。<ref name=Klein/>

==参考资料==
{{reflist}}

{{钠化合物}}
{{多氧化物}}

[[Category:钠化合物]]
[[Category:臭氧化物]]

{{inorganic-compound-stub}}