查看“︁硫酸铀(IV)”︁的源代码

{{chembox
| Verifiedfields = changed
| verifiedrevid = 403120211
|   Name = 硫酸铀(IV)
|   CustomizedImage=[[File:U4+ ion.svg|35px|Cerion]]<math>\mathrm{ \ \Biggl[}</math>[[File:Sulfate.svg|80px|Sulfation]]<math>\mathrm{ \ \!\ \Biggr]_2}</math>
|   OtherNames = 硫酸铀、二硫酸铀
|   NameEn = Uranium(IV) sulfate
| Section1 = {{Chembox Identifiers
|   ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 11383849
| InChI = 1/H2O4S.U/c1-5(2,3)4;/h(H2,1,2,3,4);/q;+2/p-2
| InChIKey = SMWCBVIJCHHBAU-NUQVWONBAD
| SMILES = [U+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/H2O4S.U/c1-5(2,3)4;/h(H2,1,2,3,4);/q;+2/p-2
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = SMWCBVIJCHHBAU-UHFFFAOYSA-L
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 14355-39-6
| CASNo_Comment = 无水
| CASNo2 = 13470-23-0
| CASNo2_Comment = 四水
| CASNo2_Ref = {{cascite|correct|CAS}}
| CASNo3 = 19086-22-7
| CASNo3_Comment = 八水
| CASNo3_Ref = {{cascite|correct|CAS}}
  }}
| Section2 = {{Chembox Properties
|   Formula = U(SO<sub>4</sub>)<sub>2</sub>
|   MolarMass =430.15（无水）<BR>502.22（四水）
|   Density = 3.6 g·cm<sup>-3</sup>（四水）<ref name=Georg />
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|Section3={{Chembox Structure
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|Section4={{Chembox Thermochemistry
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|Section5={{Chembox Pharmacology
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|Section6={{Chembox Explosive
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|Section7={{Chembox Hazards
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|Section8={{Chembox Related
| OtherAnions = [[四氯化铀]]
| OtherCations = [[硫酸钕]]<BR>[[硫酸钍]]
| OtherFunction = 
| OtherFunction_label = 
| OtherCpds = [[二氧化铀]]<BR>[[硫酸铀酰]]}}
}}
'''硫酸铀(IV)'''是一种水溶性[[铀]]化合物，化学式为U(SO<sub>4</sub>)<sub>2</sub>，高毒。

==制备==
[[硫酸铀酰]]溶液经过[[光化学]]还原可以得到硫酸铀(IV)，以[[乙醇]]为还原剂，光化学还原可以在日光下进行。硫酸铀(IV)在溶液中结晶，或者加入过量的[[乙醇]]使之沉淀。硫酸铀有多种水合物。这种光化学反应在热力学和动力学上都是有利的。

[[硫酸铀酰]]阴极还原也能得到硫酸铀(IV)：<ref name=Georg>Georg Brauer (Hrsg.): Handbuch der Präparativen Anorganischen Chemie. 3., umgearb. Auflage. Band II. Enke, Stuttgart 1978, ISBN 3-432-87813-3, S. 1245.</ref>
: UO<sub>2</sub>SO<sub>4</sub> + 2H<sub>2</sub>SO<sub>4</sub> → U(SO<sub>4</sub>)<sub>2</sub> + 4H<sub>2</sub>O

==相关物种==

U<sup>IV</sup>-SO<sub>4</sub>可以形成离子及配合物，如USO<sub>4</sub><sup>2+</sup><ref>Day Jr R A, Wilhite R N, Hamilton F D. Stability of complexes of uranium (IV) with chloride, sulfate and thiocyanate[J]. Journal of the American Chemical Society, 1955, 77(12): 3180-3182. DOI: 10.1021/ja01617a004</ref>、[U(SO<sub>4</sub>)<sub>5</sub>(H<sub>2</sub>O)]<sup>6−</sup><ref>Hennig C, Kraus W, Emmerling F, et al. Coordination of a uranium (IV) sulfate monomer in an aqueous solution and in the solid state[J]. Inorganic chemistry, 2008, 47(5): 1634-1638. DOI: 10.1021/ic701880h</ref>等。

==参考文献==
{{reflist}}

==拓展阅读==
* {{Cite journal | last1 = Perez | first1 = F. M. | last2 = Gil | first2 = J. M. | last3 = Gil | first3 = F. J. M. | title = Preparation, infrared and visible spectra of Sulfate Complexes of Uranium(IV) | doi = 10.1002/zaac.19804620127 | journal = Zeitschrift für anorganische und allgemeine Chemie| volume = 462 | pages = 231 | year = 1980 | url = http://www.researchgate.net/publication/230420833_Preparation_infrared_and_visible_spectra_of_Sulfate_Complexes_of_Uranium%28IV%29| pmc = }}
* Merkel, B.; Hasche-Berger, A. (2008). Uranium, Mining and Hydrogeology. Springer. {{ISBN|978-3-540-87745-5}}
* Hennig, C.; Schmeide, K.; Brendler, V.; Moll, H.; Tsushima, S.; Scheinost, A.C. (2007). “EXAFS Investigation of U(VI), U(IV), and Th(IV) Sulfato Complexes in Aqueous Solution”. Inorganic Chemistry 46 (15): 5882–5892.
* Cardenas, E.; Watson, D.; Gu, B.; Ginder-Vogel, M.; Kitanidis, P.K.; Jardin, P.M.; Wu, W.; Leigh, M.B.; Carley, J.; Carroll, S.; Gentry, T.; Luoe, J.; Zhou, J.; Criddle, C.S.; Marsh, T.L.; Tiedje, J.M. (2010). “Significant Association between Sulfate-Reducing Bacteria and Uranium-Reducing Microbial Communities as Revealed by a Combined Massively Parallel Sequencing-Indicator Species Approach”. Applied and Environmental Microbiology 76 (20): 6778-6786.
* Converse, B.J.; Wua, T.; Findlay, R.H.; Roden, E.E. (2013). “U(VI) Reduction in Sulfate-Reducing Subsurface Sediments Amended with Ethanol or Acetate”.  Applied and Environmental Microbiology 79 (13): 4173-4177.
* Day, R. A.; Wilhite, R. N.; Hamilton, F.R. (1955). “Stability of Complexes of Uranium(IV) with Chloride, Sulfate and Thiocyanate”. Journal of the American Chemical Society 77 (12):3180-3182.
* Hennig, C.; Kraus, W.; Emmerling, F.; Ikeda, A.;. Scheinost, A.C. (2008). “Coordination of a Uranium(IV) Sulfate Monomer in an Aqueous Solution and in the Solid State”. Inorganic Chemistry 47 (5): 1634-1638.
* Plášil, J.; Fejfarová, K.; Novák, M.; Dušek, M.; Škoda, R.; Hloušek, J.; Čejka, J.; Majzlan, J.; Sejkora, J.; Machovič, V.; Talla, D. (2011). “Běhounekite, U(SO4)2(H2O)4, from Jáchymov (St Joachimsthal), Czech Republic: the first natural U4+ sulphate”. Mineralogical Magazine 75 (6): 2739-2753.
* Mudd, G.M. (2001). “Critical Review of Acid in situ leach uranium mining: 1. USA and Australia”. Environmental Geology 41 (3-4): 390-403.
* Závodská, L.; Kosorínová, E.; Scerbáková, L.; Lesny, J. (2008). “Environmental Chemistry of Uranium”. HV {{ISSN|1418-7108}}.

{{铀化合物}}
{{硫酸盐}}

[[Category:四价铀化合物]]
[[Category:硫酸盐]]