查看“︁硫氰酸锰”︁的源代码

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| Mn=1 | C=2 | N=2 | S=2
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'''硫氰酸锰'''是一种[[无机化合物]]，化学式为Mn(SCN)<sub>2</sub>，对空气和湿气敏感。它可通过[[硫氰酸钡]]和[[硫酸锰]]的复分解反应制得：<ref name=inorg>{{cite journal|journal=Inorganic Chemistry|volume=59|issue=16|language=en|issn=0020-1669|date=2020-08-17|pages=11627–11639|doi=10.1021/acs.inorgchem.0c01478|url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c01478|title=Strengthening the Magnetic Interactions in Pseudobinary First-Row Transition Metal Thiocyanates, M(NCS) 2|accessdate=2021-11-26|author=Euan N. Bassey, Joseph A. M. Paddison, Evan N. Keyzer, Jeongjae Lee, Pascal Manuel, Ivan da Silva, Siân E. Dutton, Clare P. Grey, Matthew J. Cliffe|archive-date=2021-11-26|archive-url=https://web.archive.org/web/20211126152918/https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c01478|dead-url=no}}</ref>
:<math>\mathrm{MnSO_4 + Ba(SCN)_2 \longrightarrow BaSO_4 \downarrow + \ Mn(SCN)_2}</math>
它和[[硫氰酸汞]]反应，可以得到MnHg(SCN)<sub>4</sub>。<ref>{{cite journal|journal=Materials Research Bulletin|volume=36|issue=5-6|language=en|date=2001-03|pages=879–887|doi=10.1016/S0025-5408(01)00573-6|url=https://linkinghub.elsevier.com/retrieve/pii/S0025540801005736|title=Crystal growth and characterization of the organometallic nonlinear optical crystal: manganese mercury thiocyanate (MMTC)|accessdate=2021-11-26|author=X.Q Wang, D Xu, M.K Lu, D.R Yuan, S.X Xu|archive-date=2018-06-07|archive-url=https://web.archive.org/web/20180607052235/https://linkinghub.elsevier.com/retrieve/pii/S0025540801005736|dead-url=no}}</ref>它和乙二胺双盐酸盐反应，可以得到聚合物{(C<sub>2</sub>H<sub>10</sub>N<sub>2</sub>)(MnCl(NCS)<sub>2</sub>)<sub>2</sub>}<sub>n</sub>。<ref>{{cite journal | title=Synthesis, X-ray powder diffraction study, thermal analysis, Hirshfeld surface analysis and optical properties of new crystalline polymer: {(C2H10N2)(MnCl(NCS)2)2}n | journal=Journal of Molecular Structure | volume=1223 | date=2021-01-05 | issn=0022-2860 | doi=10.1016/j.molstruc.2020.128993 | url=https://www.sciencedirect.com/science/article/pii/S0022286020313168?via%3Dihub | access-date=2021-11-26 | page=}}</ref>

==参考文献==
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{{锰化合物}}
{{硫氰酸盐}}

[[Category:二价锰化合物]]
[[Category:硫氰酸盐]]