查看“︁硫氰酸钡”︁的源代码
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{{Chembox <!-- Names --> | Name = Barium thiocyanate | IUPACName = Barium thiocyanate | PIN = | SystematicName = | OtherNames = 硫氰化钡 |CustomizedImage=[[File:2.svg]][[File:Thiocyanat-Ion.svg]][[File:Ba2+.svg]] <!-- Sections --> | Section1 = {{Chembox Identifiers | CASNo1 = 68016-36-4 | CASNo = 2092-17-3 | CASNo_Comment = 无水 | CASNo1_Comment = 三水 | CASNo1_Ref = {{cascite|correct|CAS}} | CASNo_Ref = {{cascite|correct|CAS}} | ChEBI = | ChemSpiderID = 144591 | EINECS = | EC_number = 218-245-9 | Gmelin = | KEGG = | MeSHName = | PubChem = 164928 | RTECS = | UNNumber = | UNII = 3412AZ8I1A | StdInChI=1S/2CHNS.Ba/c2*2-1-3;/h2*3H;/q;;+2/p-2 | StdInChIKey = LKZCRGABYQYUFX-UHFFFAOYSA-L | SMILES = C(#N)[S-].C(#N)[S-].[Ba+2] }} | Section2 = {{Chembox Properties | Appearance = 无色晶体 | BoilingPt = | Density = | Formula = Ba(SCN)<sub>2</sub> | MolarMass = 253.49 | MeltingPt = | Solubility = 62.63 g/100 ml (25°C) | SolubleOther = 可溶于[[丙酮]]、[[甲醇]]和[[乙醇]] }} | Section7 = {{Chembox Hazards | AutoignitionPt = | ExploLimits = | FlashPt = | LD50 = | LC50 = | MainHazards = | NFPA-F = | NFPA-H = | NFPA-R = | NFPA-S = | PEL = | REL = | ExternalSDS = | GHSPictograms = {{GHS07}} | GHSSignalWord = | HPhrases = {{H-phrases|301|312|315|319|332|335}} | PPhrases = {{P-phrases|261|280|302+352|304+340}} }} | Section9 = {{Chembox Related | OtherAnions = [[硒氰酸钡]] | OtherCations = | OtherFunction = | OtherFunction_label = | OtherCpds = }} }} '''硫氰酸钡'''是一种[[无机化合物]],化学式为Ba(SCN)<sub>2</sub>。它可由[[硫氰酸铵]]和[[氢氧化钡]]反应得到<ref>Herstein, Karl M. Barium thiocyanate. ''Inorganic syntheses. III'', 1950. 24-26.</ref>,或通过[[硫氰酸钠]]和[[氯化钡]]在340 °C反应制得。<ref>Wickleder, Claudia. M(SCN)<sub>2</sub> (M = Eu, Sr, Ba). Crystal structure, thermal behavior, vibrational spectroscopy. ''Zeitschrift fuer Anorganische und Allgemeine Chemie'', 2001. 627 (7): 1693-1698.</ref>它可用于制备其它金属的硫氰酸盐,如[[硫氰酸钴]]:<ref>{{cite journal|journal=Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry|volume=32|issue=5|issn=0567-7408|date=1976-05-01|pages=1526–1529|doi=10.1107/S0567740876005694|url=http://scripts.iucr.org/cgi-bin/paper?S0567740876005694|title=The crystal structure of cobalt(II) thiocyanate trihydrate|accessdate=2021-11-26|author=F. H. Cano, S. García-Blanco, A. G. Laverat|archive-date=2021-11-26|archive-url=https://web.archive.org/web/20211126152526/http://scripts.iucr.org/cgi-bin/paper?S0567740876005694|dead-url=no}}</ref> :<math>\mathrm{CoSO_4 + Ba(SCN)_2 \longrightarrow BaSO_4 \downarrow + \ Co(SCN)_2}</math> ==参考文献== {{reflist}} {{钡化合物}} {{硫氰酸盐}} [[Category:钡化合物]] [[Category:硫氰酸盐]]
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