查看“︁硫化铋”︁的源代码

{{chembox
| verifiedrevid = 440749968
| ImageFile =Sulfid bismutitý.PNG
| ImageSize =
| ImageName = 硫化铋
| IUPACName = Bismuth(III) sulfide
| Section1 = {{Chembox Identifiers
|   ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 141425
| InChI = 1/2Bi.3S/q2*+3;3*-2
| InChIKey = YNRGZHRFBQOYPP-UHFFFAOYAA
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/2Bi.3S/q2*+3;3*-2
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = YNRGZHRFBQOYPP-UHFFFAOYSA-N
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 1345-07-9
|   PubChem = 
|   SMILES = [Bi+3].[Bi+3].[S-2].[S-2].[S-2]
}}
| Section2 = {{Chembox Properties
|   Formula = Bi<sub>2</sub>S<sub>3</sub>
|   MolarMass = 514.16
|   Appearance =  暗棕色粉末
|   Density = 6.78 g/cm<sup>3</sup><ref Name="webelements">[http://www.webelements.com/webelements/compounds/text/Bi/Bi2S3-1345079.html WebElements Periodic Table of the Elements<!-- Bot generated title -->]</ref>
|   MeltingPt = 775 ˚C<ref Name="J. Phys. Chem.">[http://dx.doi.org/10.1021/j100812a516 D. Cubicciotti, "The Bismuth-Sulfur Phase Diagram," J. Phys. Chem., 66, 1205, (1962).]</ref>
|   BoilingPt = 
|   Solubility = 不溶
|   SolubleOther = 不溶于酸
  }}
| Section3 = {{Chembox Structure
|  Reference = 
|  CrystalStruct = 三方晶系
|  SpaceGroup = 
|  Coordination = 
|  LattConst_a = 
|   LattConst_b = 
|   LattConst_c = 
|  LattConst_alpha = 
|   LattConst_beta = 
|   LattConst_gamma = 
|  MolShape = 
|  OrbitalHybridisation = 
|  Dipole =  }}
| Section4 = {{Chembox Hazards
|   MainHazards = 刺激性
|   RPhrases = {{R36/37/38}}
|   SPhrases = {{S26}}, {{S37}}
|   FlashPt = 
|   Autoignition = 
  }}
}}
'''硫化铋'''是铋的硫化物，化学式Bi<sub>2</sub>S<sub>3</sub>，是[[辉铋矿]]的主要成分。它可用于生产其它铋化合物。<ref>{{cite book | last=Patnaik | first=Pradyot | title=Handbook of inorganic chemicals | url=https://archive.org/details/Handbook_of_Inorganic_Chemistry_Patnaik | publisher=McGraw-Hill | publication-place=New York | date=2003 | isbn=0-07-049439-8 | oclc=50252041}}</ref>

==制备==
Bi(III)盐的水溶液与[[硫化氢]]反应生成黑色的硫化铋沉淀：

:<math>\mathrm{2 \ Bi^{3+} + 3 \ H_2S \longrightarrow \ Bi_2S_3 + 6 \ H^+}</math>

硫化铋也能通过铋与硫单质于500℃共热96小时制得。

:<math>\mathrm{2 \ Bi + 3 \ S \longrightarrow \ Bi_2S_3 }</math>
==性质==
硫化铋溶于硝酸或热的浓高氯酸,但不溶于碱及硫化铵。硫化铋与[[硫化锑]]同晶，具有复杂的网状结构。<ref>张青莲主编. 无机化学丛书_第四卷.氮磷砷分族. 高等教育出版社, 1998 :499.</ref>
硫化铋也易溶于除氢氟酸以外的氢卤酸。<ref>刘狄，李大塘. 硫化铋溶解性的热力学研究。 湖南城市学院学报:自然科学版: 2007</ref>

==参考资料==
<references/>
{{铋化合物}}
[[Category:铋化合物]]
[[Category:硫化物]]