查看“︁硫化鍶”︁的源代码

{{chembox
| verifiedrevid = 382666003
| Reference=<ref>[http://cameochemicals.noaa.gov/chemical/21036 Strontium sulfide] {{Wayback|url=http://cameochemicals.noaa.gov/chemical/21036 |date=20090424075854 }}, cameochemicals.noaa.gov</ref>
| ImageFile = NaCl polyhedra.svg
| IUPACName = 
|   OtherNames = 
| Section1 = {{Chembox Identifiers
|   CASNo = 1314-96-1
|    CASNo_Ref = {{cascite}}
|   PubChem = 
| SMILES = [S-2].[Sr+2]
  }}
| Section2 = {{Chembox Properties
|   Formula = SrS
|   MolarMass = 119.68
|   Appearance = 白色固体<ref name="brauer" />
|   Density = 3.65 g/cm<sup>3</sup><ref name="brauer" />
|   MeltingPt = 2226°C<ref name="W. M. Haynes, David R. Lide, Thomas J. Bruno" />
|   BoilingPt = 
|   Solubility = 微溶<ref name="W. M. Haynes, David R. Lide, Thomas J. Bruno">{{cite book| author= W. M. Haynes, David R. Lide, Thomas J. Bruno | title= CRC Handbook of Chemistry and Physics 2012-2013 | publisher= CRC Press | ISBN = 143988049-2 | date= 2012 | pages = 4-92 }}</ref>
|   SolubleOther =遇[[酸]]分解<br />可溶于乙醇<ref name="W. M. Haynes, David R. Lide, Thomas J. Bruno" />
  }}
| Section3 = {{Chembox Structure
|   CrystalStruct = [[岩鹽]]（立方晶系），[[皮尔逊符号|cF8]]
|   SpaceGroup = Fm<u style="text-decoration:overline">3</u>m, No. 225
|   Coordination = 八面體 （Sr<sup>2+</sup>）；八面體（S<sup>2–</sup>）
|   LattConst_a = 
  }}| Section7 = {{Chembox Hazards
|   ExternalMSDS = [http://msds.chem.ox.ac.uk/ST/strontium_sulfide.html External MSDS]
|   EUIndex = 沒列出
|   EUClass = 
|   RPhrases = 
|   SPhrases = 
|   NFPA-H = 
|   NFPA-F = 
|   NFPA-R = 
|   NFPA-O = 
  }}
| Section8 = {{Chembox Related
|   OtherAnions = [[氧化鍶]]<br />[[硒化锶]]<br />[[碲化锶]]
|   OtherCations = [[硫化铍]]<br />[[硫化鎂]]<br/>[[硫化鈣]]<br/>[[硫化鋇]]
|   OtherFunctn = 
|    Function = 
|   OtherCpds = [[硫酸锶]]
  }}
}}

'''硫化鍶'''，化學式為SrS，是一种白色固体。硫化锶是把重要的锶矿[[天青石]]（硫酸锶）转换成其它锶化合物的中间体。<ref name=Ullmann>J. Paul MacMillan, Jai Won Park, Rolf Gerstenberg, Heinz Wagner, Karl Köhler, Peter Wallbrecht  “Strontium and Strontium Compounds” in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim. {{DOI|10.1002/14356007.a25_321}}.</ref><ref name=Celestine>{{Cite web |url=https://www.mindat.org/min-927.html |title=存档副本 |access-date=2021-06-26 |archive-date=2021-10-20 |archive-url=https://web.archive.org/web/20211020002707/https://www.mindat.org/min-927.html |dead-url=no }}</ref><ref name=IMA>{{Cite web |url=https://www.ima-mineralogy.org/Minlist.htm |title=存档副本 |access-date=2021-06-26 |archive-date=2021-12-20 |archive-url=https://web.archive.org/web/20211220223545/https://www.ima-mineralogy.org/Minlist.htm |dead-url=no }}</ref>因其點燃是有亮紅色火焰而用作[[煙火]]的添加劑，也可用於[[脫毛]]<ref name="Robert E. Krebs">{{cite book| author= Robert E. Krebs | title= The History And Use of Our Earth's Chemical Elements: A Reference Guide | url= https://archive.org/details/historyuseofoure0000kreb | publisher= Greenwood Publishing Group | ISBN = 031333438-2 | date= 2006 |page = [https://archive.org/details/historyuseofoure0000kreb/page/n105 78] }}</ref>和夜光[[塗料]]的熒光粉。 

== 製備 ==
硫化锶可以由天青石和[[焦炭]]在110–1300&nbsp;°C下反应而成。<ref name=hydrometallurgy>{{cite journal |journal= Hydrometallurgy |volume= 84 |issue= 3–4 |year= 2006 |pages= 239–246 |title= Dissolution kinetics of celestite (SrSO<sub>4</sub>) in HCl solution with BaCl<sub>2</sub> |first1= Salih |last1= Aydoğan |first2= Murat |last2= Erdemoğlu |first3= Ali |last3= Aras |first4= Gökhan |last4= Uçar |first5= Alper |last5= Özkan |doi= 10.1016/j.hydromet.2006.06.001 }}</ref>其中，天青石的硫酸根被[[还原]]成硫离子：
:SrSO<sub>4</sub>  + 2 C   →   SrS  +  2 CO<sub>2</sub>
每年约有300,000吨的硫化锶被这样制造。<ref name=Ullmann/>

硫化鍶可通過硫和锶直接在惰性气氛中反应而成：{{cn}}
:<math>\mathrm{Sr + S \rightarrow SrS}</math>

它也可以由[[碳酸锶]]在1000 °C和[[硫化氢]]蒸汽反应而成。<ref name="brauer">[[Georg Brauer]] (Hrsg.), unter Mitarbeit von [[Marianne Baudler]] u.&nbsp;a.: ''Handbuch der Präparativen Anorganischen Chemie.'' 3., umgearbeitete Auflage. Band II, Ferdinand Enke, Stuttgart 1978, ISBN 3-432-87813-3, S. 927.</ref>

== 參考資料 ==
{{reflist}}

==拓展鏈接==
* [https://web.archive.org/web/20110707133424/http://www.americanelements.com/srsf.html American Elements]

{{鍶化合物}}
{{硫化物}}
[[Category:锶化合物]]
[[Category:硫化物]]
[[Category:缺少物质图片的化学品条目]]