查看“︁甲酸铷”︁的源代码

{{Chembox
| ImageFileL1  = Formate-anion.svg
| ImageFileR1=Rb+.svg
| ImageSizeR1=35px
| OtherNames  =
| Section1={{Chembox Identifiers
| CASNo           = 3495-35-0
| CASNo_Ref = {{cascite|correct|CAS}}
| EC-number       = 624-445-0
| ECHA-ID         = 100.153.035
| PubChem         = 23673641
| ChemSpider      = 
| SMILES=[Rb+].[O-]C=O
}}
| Section2={{Chembox Properties
| Appearance    = 易潮解<ref name="Catalog">"Catalog Handbook of Fine Chemicals", Verlag Aldrich Chemical Co., 2000, S. 1470. ({{Google Buch|BuchID=9N05AAAAMAAJ|Seite=1470}})</ref> 的白色粉末<ref name="Alfa">{{Alfa|13499|Datum=26. Mai 2010}}</ref>
| C=1|H=1|O=2|Rb=1
| Density          = 
| MeltingPt    = 170 [[摄氏度|°C]]<ref>D. Leonesi, G. Berchiesi, A. Cingolani: "Electric Conductivity in Molten Binaries of Alkali Formates and Acetates", in: ''J. Chem. Eng. Data'', '''1975''', ''20''(1), S.&nbsp;31–32; {{doi|10.1021/je60064a026}}.</ref>
| BoilingPt      = 
| Solubility     = 可溶<ref name="Alfa"/>
}}
| Section8={{Chembox Related
| OtherCations=[[甲酸锂]]<br />[[甲酸钠]]<br />[[甲酸钾]]<br />[[甲酸铯]]
| OtherAnions=[[碳酸铷]]<br />[[乙酸铷]]
}}
}}

'''甲酸铷'''是[[铷]]的[[甲酸盐]] ，[[化学式]] HCOORb。

== 制备 ==
甲酸铷可以由[[甲酸]]和[[氢氧化铷]]中和而成。

: <chem>RbOH + HCOOH -> HCOORb + H2O</chem>

它也可以由[[碳酸铷]]和甲酸反应而成，会放出[[二氧化碳]]。<ref name="Sidgwick">N. V. Sidgwick, J. A. H. R. Gentle: "The solubilities of the alkali formates and acetates in water" in ''J. Chem. Soc., Trans.'' '''1922''', ''121'', S. 1837–1843 {{DOI|10.1039/CT9222101837}}</ref>

: <chem>Rb2CO3 + 2HCOOH -> 2HCOORb + CO2 ^ + H2O</chem>

[[氢化铷]]和[[二氧化碳]]直接反应也可以得到甲酸铷。<ref name="Abegg">R. Abegg, F. Auerbach: ''Handbuch der anorganischen Chemie.'' Verlag S. Hirzel, Bd. 2, 1908. S. 425.[http://www.archive.org/stream/handbuchderanor09koppgoog#page/n445/mode/2up Volltext]</ref><ref name="TB">"A Text-Book of Inorganic Chemistry", Verlag Forgotten Books, ISBN 978-1-4510-0469-4. S. 209. ({{Google Buch|BuchID=C42fSjVzmkAC|Seite=209}})</ref>

:<chem>RbH + CO2 -> HCOORb</chem>

== 参考资料 ==
{{reflist}}
{{铷化合物}}
{{甲酸盐}}

[[Category:铷化合物]]
[[Category:甲酸盐]]