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氯化镁
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{{Chembox | ImageFile = Magnesium chloride.jpg | ImageSize = 200px | ImageFile1 = Magnesium-chloride-3D-polyhedra.png | IUPACName = Magnesium chloride | SystematicName = | OtherNames = | Section1 = {{Chembox Identifiers | CASNo = 7786-30-3 | CASNo_Comment = 无水物 | CASNo_Ref = {{cascite|correct|CAS}} | CASNo1 = 7791-18-6 | CASNo1_Comment = 六水合物 | CASNo1_Ref = {{cascite|correct|CAS}} | Abbreviations = | EINECS = | PubChem = | SMILES = | InChI = | RTECS = OM2975000 | MeSHName = | ChEBI = | KEGG = | ATCCode_prefix = | ATCCode_suffix = | ATC_Supplemental = | ChEMBL_Ref = {{ebicite|changed|EBI}}| ChEMBL = 1200547 | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}| ChemSpiderID = 22987 | ChEBI_Ref = {{ebicite|correct|EBI}}| StdInChI_Ref = {{stdinchicite|correct|chemspider}}| StdInChI = 1S/2ClH.Mg/h2*1H;/q;;+2/p-2 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}| StdInChIKey = TWRXJAOTZQYOKJ-UHFFFAOYSA-L | Gmelin = 9305 }} | Section2 = {{Chembox Properties | Formula = MgCl<sub>2</sub> (无水)<br>MgCl<sub>2</sub>·6H<sub>2</sub>O (六水) | MolarMass = 95.211 g/mol (无水)<br>203.31 g/mol (六水) | Appearance = 白色或无色晶体 | Density = 2.32 g/cm³ (无水)<br>1.56 g/cm³ (六水) | MeltingPt = 714 °C (987 K) | Melting_notes = | BoilingPt = 1 412 °C (1 685 K) | Boiling_notes = | Solubility = | Solubility1 = 7.4 g/100 mL (30 °C) | Solvent1 = 乙醇 | SolubleOther = | Solvent = | LogP = | VaporPressure = | HenryConstant = | AtmosphericOHRateConstant = | pKa = | pKb = }} | Section3 = {{Chembox Structure | CrystalStruct = [[氯化镉|CdCl<sub>2</sub>]] | Coordination = 六配位八面体 | MolShape = }} | Section4 = {{Chembox Thermochemistry | DeltaHf = | DeltaHc = | Entropy = | HeatCapacity = }} | Section5 = {{Chembox Pharmacology | AdminRoutes = | Bioavail = | Metabolism = | HalfLife = | ProteinBound = | Excretion = | Legal_status = | Legal_US = | Legal_UK = | Legal_AU = | Legal_CA = | PregCat = | PregCat_AU = | PregCat_US = }} | Section6 = {{Chembox Explosive | ShockSens = | FrictionSens = | ExplosiveV = | REFactor = }} | Section7 = {{Chembox Hazards | EUClass = | EUIndex = | MainHazards = 刺激性 | NFPA-H = 2 | NFPA-F = 0 | NFPA-R = 0 | NFPA-O = | RPhrases = {{R36}}, {{R37}}, {{R38}} | SPhrases = {{S22}},{{S23}},{{S24}},{{S25}} | RSPhrases = | FlashPt = | Autoignition = | ExploLimits = | LD50 = | PEL = }} | Section8 = {{Chembox Related | OtherAnions = [[氟化镁]]<br> [[溴化镁]]<br> [[碘化镁]] | OtherCations = [[氯化铍]]<br>[[氯化钙]]<br>[[氯化锶]]<br>[[氯化钡]] | OtherFunctn = | Function = | OtherCpds = }} }} {{Expand English|Magnesium chloride}} '''氯化镁'''是一种[[氯化物]],[[化学式]]MgCl<sub>2</sub>。无色而易[[潮解]][[晶体]]。這些鹽是典型的離子鹵化物,高度易溶於水。水合氯化鎂可以從鹽水或[[海水]]中提取。通常带有6[[分子]]的[[结晶水]]。但加热至95[[摄氏度|℃]]时失去结晶水。135℃以上时开始分解,并释放出[[氯化氢]](HCl)气体。工业上生产[[镁]]的原料。在海水和[[盐卤]]中找到。水合氯化鎂是處方口服鎂補充劑通常使用的物質。氯化鎂水溶液呈中性。 ==制备== 氯化镁一般用[[氢氧化镁]]和[[盐酸]]經過中和得到: :<chem>2HCl + Mg(OH)2->MgCl2 + 2H2O</chem> 此外,镁的氧化物、碳酸盐和盐酸反应,也能制得氯化镁。此外,[[鹽酸|氫氯酸]]和鎂亦可制得氯化鎂: :<chem>2HCl + Mg->MgCl2 + H2</chem> ==毒物學== 鎂離子有苦味,氯化鎂溶液的苦的程度,取決於不同程度的鎂離子濃度。氯化鎂一旦滲入泥土,會造成[[鎂害]]<ref name="colostate1">{{Cite web |title=Magnesium Chloride Toxicity in Trees |url=http://www.ext.colostate.edu/pubs/garden/07425.html |website=www.ext.colostate.edu |language=en |last=Colorado State University Extension |access-date=2025-01-26}}</ref><ref>{{Cite web |title=Pesticide Info {{!}} Search by a chemical or product |url=https://www.pesticideinfo.org:443/ |website=www.pesticideinfo.org |language=en |access-date=2025-01-26}}</ref>。 ==參考資料== {{reflist}} ==外部連結== {{鎂化合物}} {{氯化物}} {{矿物补充剂}} [[Category:氯化物]] [[Category:金属卤化物]] [[Category:碱土金属卤化物]] [[Category:化學肥料]] [[Category:有E编码的食品添加剂]]
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