查看“︁氯化錫”︁的源代码

{{Chembox
| Name = 氯化锡
| ImageFile = Tin(IV) chloride pentahydrate.jpg
| ImageFile1 = Tin(IV) chloride.jpg
| ImageName = Tin(IV) chloride
| IUPACName = Tin tetrachloride<br />Tin(IV) chloride
| OtherNames = 四氯化锡，氯化锡（IV）
| Section1 = {{Chembox Identifiers
| CASNo = 7646-78-8
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo_Comment = 无水
| CASNo1 = 10026-06-9
| CASNo1_Comment =  五水
| CASNo1_Ref = {{cascite|correct|CAS}}
|  ChemSpiderID_Ref  = {{chemspidercite|correct|chemspider}}|  ChemSpiderID  =  22707
|  InChI  =  1/4ClH.Sn/h4*1H;/q;;;;+4/p-4
|  InChIKey  =  HPGGPRDJHPYFRM-XBHQNQODAC
|  SMILES  =  Cl[Sn](Cl)(Cl)Cl
|  StdInChI_Ref  = {{stdinchicite|correct|chemspider}}|  StdInChI  =  1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4
|  StdInChIKey_Ref  = {{stdinchicite|correct|chemspider}}|  StdInChIKey  =  HPGGPRDJHPYFRM-UHFFFAOYSA-J
|  EINECS  =  231-588-9
|  RTECS  =  XP8750000
|  UNNumber  =  1827
|  PubChem  =  24287
}}
| Section2 = {{Chembox Properties
| Formula = SnCl<sub>4</sub>
| MolarMass = 260.50(無水) <br> 350.60(五水合)
| Appearance = 发烟液体
| Density = 2.226(無水)<ref>"Metal-Organics Catalog" physical property data were obtained from Gelest, Inc. of Morrisville, Pennsylvania (US). Retrieved from SciFinder. [2020-1-4].</ref> <br> 2.04(五水合)
| Solubility = 分解(無水) <br> 極易溶 (五水合)<ref name=Handbook>Handbook of Chemistry and Physics ,94th edition,2013-2014</ref>
| MeltingPt = -34.07&nbsp;°C (無水) <br> 56&nbsp;°C (五水合)<ref name=Handbook />
| BoilingPt = 114.1&nbsp;°C
| Viscosity = ? c[[泊 (单位)|P]]
  }}
| Section4 = {{Chembox Thermochemistry
| DeltaHf =
| Entropy =
  }}
| Section7 = {{Chembox Hazards
| EUHazardSymbol = {{Chembox EUHazardSymbol|C}}
| RPhrases = {{R34}}-{{R52/53}}
| SPhrases = {{S1/2}}-{{S7/8}}-{{S26}}-{{S45}}-{{S61}}
  }}
| Section8 = {{Chembox Related
| OtherAnions = [[四氟化锡]]<br />[[四溴化锡]]<br />[[四碘化锡]]
| OtherCations = [[二氯化锡]]<br />[[四氯化锗]]<br />[[四氯化铅]]}}
}}
'''氯化錫'''，化學式[[錫|Sn]][[氯|Cl]]{{sub|4}}，為無色發煙性液體。

== 製備 ==

可於[[氯化亞錫]]溶液中，通入過量的[[氯气]]而製得。反應式：

: <math>\ SnCl_2+Cl_2\to SnCl_4</math>

== 用途 ==

氯化錫的蒸氣與[[氨]]及[[水|水氣]]混合，生成[[氫氧化錫]]及[[氯化銨]]之微粒而呈濃煙狀，[[軍事]]上用以製作[[煙幕彈]]。反應式：

: <math>\ SnCl_4+4NH_3+4H_2O\to Sn(OH)_4+4NH_4Cl</math>

==参考文献==
{{reflist}}

{{锡化合物}}
{{氯化物}}
[[Category:氯化物]]
[[Category:四氯化物]]
[[Category:卤化锡]]
[[Category:锡-氯化合物]]