查看“︁氯三溴甲烷”︁的源代码

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| C=1 | Cl=1 | Br=3
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'''氯三溴甲烷'''是一种[[有机化合物]]，化学式为CBr<sub>3</sub>Cl。它与[[烯烃]]反应，以溴和氯二溴甲基加成。<ref>{{cite journal|journal=Angewandte Chemie International Edition|volume=56|issue=30|language=en|date=2017-07-17|pages=8780–8784|doi=10.1002/anie.201704074|url=https://onlinelibrary.wiley.com/doi/10.1002/anie.201704074|title=Rhodium-Catalyzed Enantioselective Radical Addition of CX 4 Reagents to Olefins|accessdate=2021-11-02|author=Bo Chen, Cheng Fang, Peng Liu, Joseph M. Ready|pmid=28544237|pmc=5672916|archive-date=2021-11-05|archive-url=https://web.archive.org/web/20211105015723/https://onlinelibrary.wiley.com/doi/10.1002/anie.201704074|dead-url=no}}</ref><ref>Vasil'eva, T. T.; Dostovalova, V. I.; Germanova, L. F.; Nelyubin, B. V. Radical addition of polyhalomethanes to olefins and dienes. ''Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya'', 1984. 1810-1814. {{issn|0002-3353}}.</ref>

==制备==
氯三溴甲烷可由[[四氯化碳]]和[[三溴化铝]]回流反应得到，<ref name=tanaka>{{cite journal|journal=J. Chem. Soc., Perkin Trans. 2|issue=11|language=en|issn=0300-9580|date=1980|pages=1714–1720|doi=10.1039/P29800001714|url=http://xlink.rsc.org/?DOI=P29800001714|title=Nucleophilic attack on halogeno(phenyl)acetylenes by halide ions|accessdate=2021-11-02|author=Ryuichi Tanaka, Shì-Qín Zhèng, Kenji Kawaguchi, Takehide Tanaka}}</ref>或通过[[氯代环己烷]]和[[四溴化碳]]在[[三溴化铁]]的催化下反应制得。<ref>{{cite journal|journal=The Journal of Organic Chemistry|volume=54|issue=13|language=en|issn=0022-3263|date=1989-06|pages=3028–3036|doi=10.1021/jo00274a013|url=https://pubs.acs.org/doi/abs/10.1021/jo00274a013|title=Catalytic bromide and iodide exchange of alkyl chlorides with hydrogen bromide and hydrogen iodide|accessdate=2021-11-02|author=K. B. Yoon, J. K. Kochi|archive-date=2021-11-05|archive-url=https://web.archive.org/web/20211105015739/https://pubs.acs.org/doi/abs/10.1021/jo00274a013|dead-url=no}}</ref>
: <chem> CCl4 + AlBr3 -> CBr3Cl + AlCl3 </chem>
: <chem> CBr4 + C6H11Cl -> CBr3Cl + C6H11Br </chem>
二溴甲醛肟和氯化汞水溶液反应，再和[[溴]]、[[乙酸钠]]反应，得到亚硝基氯二溴甲烷，再与溴回流反应，也能得到氯三溴甲烷。<ref>{{cite book | last=Katritzky | first=A.R. | last2=Gilchrist | first2=T.L. | last3=Meth-Cohn | first3=O. | last4=Rees | first4=C.W. | title=Comprehensive Organic Functional Group Transformations | publisher=Elsevier Science | series=Comprehensive Organic Functional Group Transformations | issue=v. 6 | year=1995 | isbn=978-0-08-042704-1 | url=https://books.google.com.sg/books?id=YzBveZGm0GEC&pg=PA222 | access-date=2021-11-02 | page=222 | archive-date=2021-11-04 | archive-url=https://web.archive.org/web/20211104234326/https://books.google.com.sg/books?id=YzBveZGm0GEC&pg=PA222 | dead-url=no }}</ref>

==参考文献==
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{{卤代甲烷}}

{{Authority control}}
[[Category:卤代甲烷]]
[[Category:氯代烷烃]]
[[Category:溴代烷烃]]
[[Category:三溴甲基化合物]]