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氧化铜
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{{Chembox | ImageFile = copperIIoxide.jpg | ImageSize = | IUPACName = Copper(II) oxide | OtherNames = 氧化铜(II) | Formula = CuO | Section1 = {{Chembox Identifiers | CASNo = 1317-38-0 | CASNo_Ref = {{cascite|correct|CAS}} | Abbreviations = | EINECS = | PubChem = | SMILES = | InChI = | RTECS = | MeSHName = | ChEBI = | KEGG = | ATCCode_prefix = | ATCCode_suffix = | ATC_Supplemental = | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}| ChemSpiderID = 144499 | ChEBI_Ref = {{ebicite|changed|EBI}}| ChEMBL_Ref = {{ebicite|changed|EBI}}| ChEMBL = 1909057 | UNII_Ref = {{fdacite|correct|FDA}}| UNII = V1XJQ704R4 | InChIKey = QPLDLSVMHZLSFG-PHEGLCPBAN | InChI1 = 1/Cu.O/q+2;-2 | InChIKey1 = KKCXRELNMOYFLS-UHFFFAOYAT | SMILES1 = [Cu+2].[O-2] | StdInChI_Ref = {{stdinchicite|correct|chemspider}}| StdInChI = 1S/Cu.O/q+2;-2 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}| StdInChIKey = KKCXRELNMOYFLS-UHFFFAOYSA-N }} | Section2 = {{Chembox Properties | MolarMass = 79.545 <ref name=" CRC Handbook of Chemistry and Physics 97th Edition "/> | Formula = CuO | Appearance = 黑色粉末或单斜晶体<ref name=" CRC Handbook of Chemistry and Physics 97th Edition "> {{Cite book | date = 2016-06-24 | title = CRC Handbook of Chemistry and Physics 97th Edition | accessdate = 2017-10-14 | pages = 4-60 | language = 英语 | ISBN = 1-4987-5428-7 | }} </ref> | Density = 6.31 g/cm<sup>3</sup><ref name=" CRC Handbook of Chemistry and Physics 97th Edition "/> | MeltingPt = 1227 °C (1500 K)<ref name=" CRC Handbook of Chemistry and Physics 97th Edition "/> | Melting_notes = | BoilingPt = | Boiling_notes = | Solubility = 难溶<ref name=" CRC Handbook of Chemistry and Physics 97th Edition "/> | SolubleOther = 溶于稀酸<ref name=" CRC Handbook of Chemistry and Physics 97th Edition "/> | Solvent = | BandGap = 1.2 | pKa = | pKb = }} | Section3 = {{Chembox Structure | CrystalStruct = [[单斜]]<ref name=" CRC Handbook of Chemistry and Physics 97th Edition "/> | Coordination = | MolShape = }} | Section4 = {{Chembox Thermochemistry | DeltaHf = | DeltaHc = | Entropy = | HeatCapacity = }} | Section5 = {{Chembox Pharmacology | AdminRoutes = | Bioavail = | Metabolism = | HalfLife = | ProteinBound = | Excretion = | Legal_status = | Legal_US = | Legal_UK = | Legal_AU = | Legal_CA = | PregCat = | PregCat_AU = | PregCat_US = }} | Section6 = {{Chembox Explosive | ShockSens = | FrictionSens = | ExplosiveV = | REFactor = }} | Section7 = {{Chembox Hazards | ExternalMSDS = [http://www.sciencelab.com/xMSDS-Cupric_oxide-9923595 ScienceLab.com] | EUClass = | EUIndex = | MainHazards = | NFPA-H = 2 | NFPA-F = 0 | NFPA-R = 1 | NFPA-O = | RPhrases = | SPhrases = | RSPhrases = | FlashPt = | Autoignition = | ExploLimits = | PEL = }} | Section8 = {{Chembox Related | OtherAnions = | OtherCations = | OtherFunctn = | Function = | OtherCpds = [[氧化亚铜]]}} }} '''氧化銅'''(化学式:CuO)是[[铜]]的[[氧化物]],为黑色固体。属于[[电解质|强电解质]]。不溶于[[水]]和[[乙醇]],溶于[[酸]]、[[氯化铵]]及[[氰化钾]]溶液,[[氨]]溶液中缓慢溶解。 ==制备== 氧化铜可由[[氢氧化铜]]的热分解制得:<ref>北京师范大学 等. 无机化学(下册)第四版. 高等教育出版社, 2003. pp 706</ref> : Cu(OH)<sub>2</sub> —<u><sup>353-363 K</sup></u>→ CuO + H<sub>2</sub>O ==化学性质== 氧化铜在一定温度下,可以被一些具有还原性的气体还原,如[[氢气]]、[[碳]]、[[一氧化碳]]、[[氨]]等: : CuO + CO → Cu + CO<sub>2</sub> : C + 2 CuO → CO<sub>2</sub>↑ + 2 Cu : <chem>CuO~+~H2 ->[\triangle] Cu~+~H2O</chem> 氧化铜和铝的混合物在灼热时会发生爆炸(铝热反应): : 3 CuO + 2 Al → 2Al<sub>2</sub>O<sub>3</sub> + 3 Cu 氧化铜可溶于酸,形成铜盐,如: : CuO + H<sub>2</sub>SO<sub>4</sub> → CuSO<sub>4</sub> + H<sub>2</sub>O : CuO + 2 HClO<sub>4</sub> → Cu(ClO<sub>4</sub>)<sub>2</sub> + H<sub>2</sub>O == 参考文献 == {{reflist}} {{铜化合物}} {{氧化物}} [[Category:氧化物]] [[Category:二价铜化合物]] [[Category:半導體材料]] [[Category:烟火着色剂]] {{Inorganic-compound-stub}}
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