查看“︁氟磺酸溴(III)”︁的源代码

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|   CASNo = 29880-59-9
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|   Formula = Br(SO<sub>3</sub>F)<sub>3</sub>
|   MolarMass = 377.09
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'''氟磺酸溴(III)'''是一种[[无机化合物]]，化学式为Br(SO<sub>3</sub>F)<sub>3</sub>。它可由S<sub>2</sub>O<sub>6</sub>F<sub>2</sub>和[[溴]]反应得到。<ref name=Cotton>F. Albert Cotton (Hrsg.): Progress in Inorganic Chemistry. Band 14. John Wiley & Sons, 2009, ISBN 0-470-16658-4, pp. 65.</ref>

==反应==
氟磺酸溴(III)可以和水发生剧烈反应并放热：<ref name=Cotton />
:<chem>4 Br(SO3F)3 + 6 H2O -> 2 Br2 + 3 O2 + 12 HSO3F</chem>

它和[[溴]]反应生成[[氟磺酸溴(I)]]：<ref>{{cite journal|journal=Journal of the American Chemical Society|volume=82|issue=2|language=en|issn=0002-7863|date=1960-01|pages=352–353|doi=10.1021/ja01487a023|url=https://pubs.acs.org/doi/abs/10.1021/ja01487a023|title=Halogen Fluorosulfonates BrSO 3 F, Br(SO 3 F) 3 and I(SO 3 F) 3|accessdate=2022-12-13|author=John E. Roberts, George H. Cady|archive-date=2022-12-13|archive-url=https://web.archive.org/web/20221213162546/https://pubs.acs.org/doi/abs/10.1021/ja01487a023|dead-url=no}}</ref>
:<chem>Br(SO3F)3 + Br2 -> 3 BrSO3F</chem>

它和[[石墨]]反应，可以得到C<sub>25.2</sub>Br(SO<sub>3</sub>F)<sub>3.8</sub>。<ref>{{cite journal|journal=Synthetic Metals|volume=30|issue=1|language=en|date=1989-04|pages=9–21|doi=10.1016/0379-6779(89)90636-X|url=https://linkinghub.elsevier.com/retrieve/pii/037967798990636X|title=Graphite intercalation studies in fluorosulfuric acid as solvent|accessdate=2022-12-13|author=M.S.R. Cader, S. Karunanithy, F. Aubke|archive-date=2018-07-02|archive-url=https://web.archive.org/web/20180702091339/https://linkinghub.elsevier.com/retrieve/pii/037967798990636X|dead-url=no}}</ref>

==参考文献==
{{reflist}}

[[Category:溴化合物]]
[[Category:氟磺酸盐]]
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