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氟硼酸镉
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{{chembox | verifiedrevid = | Name = 氟硼酸镉 | ImageFile = Cadmium tetrafluoroborate Structural Formula V1.svg | ImageSize = | ImageName = | OtherNames = 四氟合硼酸镉(II) |Section1={{Chembox Identifiers | ChemSpiderID_Ref = | ChemSpiderID = | InChI = 1S/2BF4.Cd/c2*2-1(3,4)5;/q2*-1;+2 | InChIKey = NXOFSPIMFJTFSE-UHFFFAOYSA-N | SMILES = [B-](F)(F)(F)F.[B-](F)(F)(F)F.[Cd+2] | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = | StdInChIKey_Ref = | StdInChIKey = | CASNo = 14486-19-2 | CASNo_Ref = {{cascite|correct|CAS}} | PubChem = 12886773 | RTECS = | EINECS = }} |Section2={{Chembox Properties | Formula = Cd(BF<sub>4</sub>)<sub>2</sub> | Appearance = 极易潮解的无色晶体 | Odor = 无味 | MolarMass = 286.020 g/mol | Density = 1.60 g/cm<sup>3</sup><ref>{{Cite book |title=CRC Handbook of Chemistry and Physics, 88th Edition |url=https://archive.org/details/crchandbookofche0000unse_z7a4 |last=Lide |first=David R. |publisher=Taylor & Francis |year=2007–2008 |isbn=9780849304880 |location=Boca Raton, FL |pages=}}</ref> | Solubility = 易溶 | SolubleOther = 易溶于[[乙醇]] | MeltingPt = | MeltingPt_notes = | BoilingPt = | RefractIndex = }} |Section3={{Chembox Structure | CrystalStruct = }} |Section7={{Chembox Hazards | NFPA-H = | NFPA-F = | NFPA-R = | NFPA-S = | LD50 = | REL = Ca<ref name=PGCH/> | PEL = [1910.1027] TWA 0.005 mg/m<sup>3</sup> (as Cd)<ref name=PGCH>{{PGCH|0087}}</ref> | IDLH = Ca [9 mg/m<sup>3</sup> (as Cd)]<ref name=PGCH/> }} |Section8={{Chembox Related | OtherCations = [[氟硼酸锌]] }} }} '''氟硼酸镉'''是一种[[无机化合物]],化学式为Cd(BF<sub>4</sub>)<sub>2</sub>。 ==制备== 氟硼酸镉可以通过[[氟硼酸]]的水溶液和[[碳酸镉]]或[[氧化镉]]反应来制备:<ref>{{Cite web |url=https://pubchem.ncbi.nlm.nih.gov/substance/12886773 |title=Compound Summary for PubChem CID 12886773 |last= |first= |date=2017 |website=NIH |archive-url= |archive-date= |dead-url= |access-date=}}</ref> :<chem>H3OBF4_{(aq)}{} + CdCO3_{(s)} -> Cd(BF4)2_{(aq)}{} + HCO3^{-}_{(aq)}{} + H2O_{(l)} </chem>{{cn}} :<chem>H3OBF4_{(aq)}{} + CdO_{(s)} -> Cd(BF4)2_{(aq)}{} + HO^{-}_{(aq)}{} + H2O_{(l)}</chem>{{cn}} [[氟硼酸亚硝酰]]和金属[[镉]]的[[氧化还原反应]]也能制得氟硼酸镉:<ref>{{Cite journal |last1=Hathaway |first1=B. J. |last2=Holah |first2=D. G. |last3=Underhill |first3=A. E. |date=1962 |title=The preparation and properties of some bivalent transition-metal tetrafluoroborate–methyl cyanide complexes |url= |journal=Journal of the Chemical Society |volume= |pages=2444–8 |doi=10.1039/JR9620002444}}</ref> :<chem>Cd(s) + 2NOBF4 ->[{CH_3COOC_2H_5}][{CH_3CN}] Cd(BF4)2 + 2NO</chem> ==参考文献== {{reflist}} {{镉化合物}} {{氟硼酸盐}} [[category:镉化合物]] [[category:氟硼酸盐]]
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