查看“︁氟溴碘甲烷”︁的源代码

{{Chembox
| Name = 
| NameEn = Bromofluoroiodomethane
| ImageFile = CHFBrI.png
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| IUPACName = 
| IUPACNameZh = 
| OtherNames = 溴氟碘甲烷
| Section1 = {{Chembox Identifiers
|   CASNo = 1512-27-2
|   CASNo_Ref = {{cascite|correct|CAS}}
|   PubChem = 
|   SMILES =  }}
| Section2 = {{Chembox Properties
| C=1 | H=1 | Br=1 | F=1 | I=1
|   Appearance = 对光敏感的液体
|   Density = 
|   MeltingPt = 
|   BoilingPt = {{convert|36|-|38|C|K}}（30 mmHg）<ref name=li />
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| Section3 = {{Chembox Hazards
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'''氟溴碘甲烷'''是一种[[有机化合物]]，化学式为CHBrFI，具有手性<ref>{{cite journal|journal=The Journal of Physical Chemistry A|volume=106|issue=3|language=en|issn=1089-5639|date=2002-01-01|pages=465–468|doi=10.1021/jp0116959|url=https://pubs.acs.org/doi/10.1021/jp0116959|title=Electronic Structure of Chiral Halomethanes|accessdate=2021-11-02|author=Igor Novak, Dong Bo Li, Anthony W. Potts|archive-date=2021-10-27|archive-url=https://web.archive.org/web/20211027094817/https://pubs.acs.org/doi/10.1021/jp0116959|dead-url=no}}</ref>。它可由氟溴乙酸银在180~260 °C和[[碘]]在真空中反应制得，或由[[溴二碘甲烷]]和[[氟化汞]]在60 °C反应得到。<ref name=li>{{cite journal|journal=Tetrahedron|volume=58|issue=29|language=en|date=2002-07|pages=5923–5926|doi=10.1016/S0040-4020(02)00532-X|url=https://linkinghub.elsevier.com/retrieve/pii/S004040200200532X|title=Novel synthetic approaches to CHBrFI, CHClFI and CHBrClI|accessdate=2021-11-02|author=Dong Bo Li, Siu-Choon Ng, Igor Novak}}</ref>
: <chem>CHBrI2 + HgF2 -> CHBrFI + HgI2</chem>

乙基碘化锌和[[二氟碘甲烷]]反应，可以得到二氟甲基碘化锌，它存在与氟碘甲基氟化锌的互变异构，与溴反应，也能得到氟溴碘甲烷。<ref>{{cite journal | last=Beaulieu | first=Louis-Philippe B. | last2=Schneider | first2=Jakob F. | last3=Charette | first3=André B. | title=Highly Enantioselective Simmons–Smith Fluorocyclopropanation of Allylic Alcohols via the Halogen Scrambling Strategy of Zinc Carbenoids | journal=Journal of the American Chemical Society | publisher=American Chemical Society (ACS) | volume=135 | issue=21 | date=2013-05-20 | issn=0002-7863 | doi=10.1021/ja402393w | pages=7819–7822}}</ref>
==参考文献==
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{{卤代甲烷}}

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[[Category:卤代甲烷]]
[[Category:溴代烷烃]]
[[Category:碘代烷烃]]
[[Category:氟代烷烃]]