查看“︁氟溴甲烷”︁的源代码

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| verifiedrevid = 455196803
| ImageFile = Bromofluoromethane.png
| ImageSize = 175px
| ImageFile1 = Bromofluoromethane-3D-vdW.png
| ImageSize1 = 175px
| PIN = Bromo(fluoro)methane <!-- Parentheses are used according to Subsection P-16.5.1.3 of Nomenclature of Organic Chemistry – IUPAC Recommendations and Preferred Names 2013 (Blue Book) -->
| OtherNames = 溴氟甲烷<br />CFC 31B1<br />R 31B1
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| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 55059
| SMILES1 = BrCF
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/CH2BrF/c2-1-3/h1H2
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = LHMHCLYDBQOYTO-UHFFFAOYSA-N
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 373-52-4
| PubChem = 61108
| SMILES = C(F)Br
| InChI = 1/CH2BrF/c2-1-3/h1H2
 }}
|Section2={{Chembox Properties
| Formula = CH<sub>2</sub>BrF
| MolarMass = 112.93 g/mol
| Appearance = 易挥发液体
| Density = 1.76g/cm<sup>3</sup><ref>[http://www.chemicalbook.com/ChemicalProductProperty_CN_CB6154291.htm 氟溴甲烷] {{Wayback|url=http://www.chemicalbook.com/ChemicalProductProperty_CN_CB6154291.htm |date=20191129065748 }}. Chemical Book. [2017-8-22]</ref>
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| BoilingPt = {{convert|19|C|K}}
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| MolShape = Tetrahedral
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|Section8={{Chembox Related
| OtherAnions = [[氯溴甲烷]]<BR>[[溴碘甲烷]]
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'''氟溴甲烷'''是一种混合[[卤代甲烷]]，可溶于[[乙醇]]，易溶于[[氯仿]]。

其[[标准摩尔熵]]（''S''<sup><s>o</s></sup><sub>gas</sub>）为276.3 J/(mol·K)，[[热容]]（''c<sub>p</sub>''）为49.2 J/(mol·K)。

== 制备 ==
氟溴甲烷可由[[氟甲烷]]的溴化反应制备：<ref name=Bai>白占旗, 丁元胜, 黄瑛. [http://www.ixueshu.com/document/2b7c79209d63da80.html 氟溴甲烷的制备及应用] {{Wayback|url=http://www.ixueshu.com/document/2b7c79209d63da80.html |date=20170822174433 }}[J]. 浙江化工, 2005, 36(9):30-31.</ref>
: CH<sub>3</sub>F + [[溴|Br<sub>2</sub>]] → CH<sub>2</sub>BrF + HBr
[[二溴氟甲烷]]的电解还原，或者通过和[[还原剂]][[钠汞齐]]或[[氢化三丁基锡]]的反应也能得到氟溴甲烷。

[[氟乙酸银]]和[[溴]]在50~120°C反应，可以得到氟溴甲烷：<ref name=Bai />
: FCH<sub>2</sub>COOAg + Br<sub>2</sub> → CH<sub>2</sub>FBr + AgBr + CO<sub>2</sub>

[[二溴甲烷]]和[[氟化亚汞]]反应，也能得到氟溴甲烷：<ref name=Organikis>Ασκήσεις και προβλήματα Οργανικής Χημείας Ν. Α. Πετάση 1982, pp 185, §7.2.8.；pp 186, §7.3.1.</ref>
: 2 CH<sub>2</sub>Br<sub>2</sub> + Hg<sub>2</sub>F<sub>2</sub> → 2 CH<sub>2</sub>FBr + Hg<sub>2</sub>Br<sub>2</sub>

==化学性质==
氟溴甲烷可以发生[[取代反应]]：<ref name=Organikis />
:<math>\mathrm{CH_2FBr + NaCN \xrightarrow{-NaBr} FCH_2CN \xrightarrow{+ NaCN} NCCH_2CN + NaF} </math></div>
== 应用 ==
氟溴甲烷是中间体、医药和其它化学品生产过程中的重要试剂。由于[[臭氧破坏潜势]]达0.73，其使用收到限制。它的同位素标记化合物CH<sub>2</sub>Br<sup>18</sup>F可用于放射化学。

== 参考文献 ==
{{reflist}}

==拓展阅读==
*{{cite journal | author = G. Cazzoli |author2=C. Puzzarini |author3=A. Baldacci |author4=A. Baldan |last-author-amp=yes | year = 2007 | title = Determination of the molecular dipole moment of bromofluoromethane: microwave Stark spectra and ab initio calculations | journal = J. Mol. Spectrosc. | volume = 241 | issue = 115 | pages =| pmid = | doi = 10.1016/j.jms.2006.11.004| url = }}<!--| accessdate = 2007-06-29-->
* [http://msa.lib.ohio-state.edu/suppmat/v241.i1.pp112-115//mmc1.pdf Determination of the molecular dipole moment of bromofluoromethane]{{Dead link}}

{{卤代甲烷}}

[[Category:氟代烷烃]]
[[Category:溴代烷烃]]
[[Category:卤代甲烷]]
[[Category:二卤代烃]]