查看“︁氟氧化氯”︁的源代码

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|   CASNo = 22363-68-4
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|   SMILES = O=ClF }}
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|F=1|Cl=1|O=1
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'''氟氧化氯'''（Chlorosyl fluoride）是一种[[无机化合物]]，化学式为F-Cl=O，它是[[次氟酸氯]]的[[同分异构体]]，发现于1930年。<ref name=":0">{{cite book | last=Holloway | first=John H. | last2=Laycock | first2=David | title=Advances in Inorganic Chemistry | chapter=Preparations and Reactions of Inorganic Main-Group Oxide Fluorides | publisher=Elsevier | year=1983 | issn=0898-8838 | doi=10.1016/s0898-8838(08)60107-5}}</ref>它可在[[氯酰氟]]的热分解中生成，<ref>Heras, M. J.; Aymonino, P. J.; Schumacher, H. J. Kinetics of the thermal decomposition of gaseous chloryl fluoride. ''Zeitschrift fuer Physikalische Chemie (Muenchen, Germany)'', 1959. 22: 161-178. {{issn|0044-3336}}.</ref>或在[[一氧化二氯]]和[[一氟化氯]]的反应中生成：<ref>{{cite journal|journal=Inorganic Chemistry|volume=28|issue=4|language=en|issn=0020-1669|date=1989-02|pages=675–677|doi=10.1021/ic00303a013|url=https://pubs.acs.org/doi/abs/10.1021/ic00303a013|title=Reactions of chlorine fluorides and oxyfluorides with the nitrate anion and alkali metal fluoride catalyzed decomposition of chlorine pentafluoride|accessdate=2023-03-27|author=Karl O. Christe, William W. Wilson, Richard D. Wilson|archive-date=2023-03-27|archive-url=https://web.archive.org/web/20230327194221/https://pubs.acs.org/doi/abs/10.1021/ic00303a013|dead-url=no}}</ref>
: <chem>Cl2O + ClF -> Cl2 + FClO</chem>
它不稳定，会发生歧化反应：<ref name="AH">{{cite book |last1=Haupt |first1=Axel |title=Organic and Inorganic Fluorine Chemistry: Methods and Applications |date=22 March 2021 |publisher=Walter de Gruyter GmbH & Co KG |isbn=978-3-11-065933-7 |page=139 |url=https://books.google.com/books?id=5fwkEAAAQBAJ&dq=Chlorosyl+fluoride&pg=PA618 |access-date=27 March 2023 |language=en |archive-date=2023-03-30 |archive-url=https://web.archive.org/web/20230330141910/https://books.google.com/books?id=5fwkEAAAQBAJ&dq=Chlorosyl+fluoride&pg=PA618 |dead-url=no }}</ref>
: <chem> 2FClO -> ClF + FClO2</chem>
: <chem>2FClO -> 2ClF + O2</chem>

==参考文献==
{{reflist}}

[[Category:氯化合物]]
[[Category:氟氧化物]]
[[Category:1930年代发现的物质]]