查看“︁四正丁基溴化銨”︁的源代码

{{chembox
| Watchedfields = changed
| Name =四正丁基溴化銨
| verifiedrevid = 470603098
| ImageFile = Tetrabutylammonium bromide.svg
| IUPACName=
| OtherNames = TBAB
|Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 66843
| InChI = 1/C16H36N.BrH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1
| InChIKey = JRMUNVKIHCOMHV-REWHXWOFAC
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/C16H36N.BrH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = JRMUNVKIHCOMHV-UHFFFAOYSA-M
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 1643-19-2
| ChEMBL_Ref = {{ebicite|correct|EBI}}
| ChEMBL = 60696
| PubChem = 74236
| UNII = VJZ168I98R
| ChEBI_Ref = {{ebicite|correct|EBI}}
| ChEBI = 51993
| SMILES = [Br-].CCCC[N+](CCCC)(CCCC)CCCC
| EINECS = 216-699-2
 }}
|Section2={{Chembox Properties
| Formula = C<sub>16</sub>H<sub>36</sub>BrN
| MolarMass = 322.368 g/mol
| Appearance = 白色固体
| MeltingPt = 103 °C（133 °C分解）<ref>Applied Catalysis A: General 241 (2003) 227–233</ref>
 }}
|Section3={{Chembox Hazards
| MainHazards = 有害
| GHSPictograms = {{GHS07}}{{GHS09}}
| GHSSignalWord = 警告
| HPhrases = {{H-phrases|302|315|319|335|411|412}}
| PPhrases = {{P-phrases|261|264|270|271|273|280|301+312|302+352|304+340|305+351+338|312|321|330|332+313|337+313|362|391|403+233|405|501}}
 }}
|Section4={{Chembox Related
| OtherAnions = [[四正丁基氯化铵]]<br/>[[四正丁基氟化铵]]<br/>[[四正丁基氫氧化铵]]<br/>[[四正丁基三溴化铵]]
| OtherCations =
 }}
}}

'''四正丁基溴化銨'''是一种[[季銨盐]]，[[示性式]]为<chem>[(CH3CH2CH2CH2)4N]+Br-</chem>，常用作相转移催化剂，<ref>{{OrgSynth | title = Diazo transfer by means of phase-transfer catalysis: di-tert-butyl diazomalonate | author = Henry J. Ledon | prep = cv6p0414 | collvol = 6 | collvolpages = 414 | year = 1988}}</ref>用于3-苯基丙烯醛<ref>孙宏, 张泽, 陈艳春,等. 四正丁基溴化铵催化合成3-苯基丙烯醛[J]. 化学世界, 2009, 50(4).</ref>、肉桂酸苄酯<ref>李德江, 龙德清, 付和清. 微波辐射四丁基溴化铵催化合成肉桂酸苄酯[J]. 日用化学品科学, 2003, 026(006):41-42,47.</ref>等化学品的合成。它也可用于芳香化合物的电化学溴化反应。<ref>{{cite journal|journal=Synlett|volume=30|issue=11|language=en|issn=0936-5214|date=2019-07|pages=1313–1316|doi=10.1055/s-0037-1611545|url=http://www.thieme-connect.de/DOI/DOI?10.1055/s-0037-1611545|title=Electrochemical Regioselective Bromination of Electron-Rich Aromatic Rings Using n Bu4NBr|accessdate=2020-05-05|author=Wenxia Xie, Shulin Ning, Nian Liu, Ya Bai, Shutao Wang, Siyu Wang, Lingling Shi, Xin Che, Jinbao Xiang}}{{Dead link|date=2020年7月 |bot=InternetArchiveBot |fix-attempted=yes }}</ref>

它可由[[1-溴丁烷]]和[[三正丁胺]]在[[乙腈]]溶劑中反应来制备。<ref>郭良科, 冯柏成, 张旺. 四丁基溴化铵的合成[J]. 应用化工, 2015(S1).</ref>
==参考文献==
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[[Category:四丁基铵盐]]
[[Category:溴化物]]