查看“︁四乙基碘化铵”︁的源代码
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四乙基碘化铵
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{{Chembox | ImageFile = Tetraethylammonium iodide.svg | ImageSize = 200px | PIN = ''N'',''N'',''N''-Triethylethanaminium iodide | OtherNames = Tetamon iodide; Tetramon J; TEAI |Section1={{Chembox Identifiers | CASNo = 68-05-3 | CASNo_Ref = {{cascite|correct|CAS}} | PubChem = 6225 | ChemSpiderID = 5990 | SMILES = [I-].CC[N+](CC)(CC)CC | InChI = 1/C8H20N.ClH/c1-5-9(6-2,7-3)8-4;/h5-8H2,1-4H3;1H/q+1;/p-1 | InChIKey = UQFSVBXCNGCBBW-UHFFFAOYSA-M | StdInChI = InChI=1S/C8H20N.HI/c1-5-9(6-2,7-3)8-4;/h5-8H2,1-4H3;1H/q+1;/p-1 | StdInChIKey = UQFSVBXCNGCBBW-UHFFFAOYSA-M }} |Section2={{Chembox Properties | C=8 | H=20 | I=1 | N=1 | Appearance = 无色至浅黄色晶体 | Density = 1.566 g/cm<sup>3</sup><ref name=Merck>''[[The Merck Index]]'', 10th Ed., p.1316, Rahway: Merck & Co.</ref> | MeltingPt = 280 ℃(分解) | BoilingPt = | Solubility = 可溶 }} |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }} }} '''四乙基碘化铵'''是一种[[季铵盐]],[[示性式]]为<chem>[(C2H5)4]+I-</chem>,它可由[[三乙胺]]和[[碘乙烷]]反应制得。<ref>{{cite book|location=Stuttgart|language=en|isbn=9783131426512|publisher=Georg Thieme Verlag|edition=1|date=2007|url=http://www.thieme-connect.de/products/ebooks/book/10.1055/b-003-125736|title=Science of Synthesis: Houben–Weyl Methods of Molecular Transformations: Arene-X (X=N, P)|accessdate=2021-05-17|editor=Ramsden, Bellus|doi=10.1055/sos-sd-031-01847|archive-date=2021-02-26|archive-url=https://web.archive.org/web/20210226020022/https://www.thieme-connect.de/products/ebooks/book/10.1055/b-003-125736|dead-url=no}}</ref>它和[[叠氮化亚铊]]在水溶液中加热反应,可以得到四乙基叠氮化铵。<ref>Kukushkin, I. K.; Velikanova, E. V.; Zlobin, V. A. Methods for preparation of quaternary ammonium azides. ''Izvestiya Vysshikh Uchebnykh Zavedenii, Khimiya i Khimicheskaya Tekhnologiya'', 2010. 53 (3): 108-110. ISSN: 0579-2991.</ref>它和苯硫酚铟(III)在[[甲醇]]中反应,得到[(C<sub>2</sub>H<sub>5</sub>)<sub>4</sub>N][In(C<sub>6</sub>H<sub>5</sub>S)<sub>3</sub>I]。<ref>{{cite journal|journal=Canadian Journal of Chemistry|volume=65|issue=4|language=en|issn=0008-4042|date=1987-04-01|pages=804–809|doi=10.1139/v87-136|url=http://www.nrcresearchpress.com/doi/10.1139/v87-136|title=Coordination compounds of indium. Part 43. Indium(III) derivatives of benzenethiol, and the crystal structure of tetraphenylphosphonium bromotris(benzenethiolato)- indate(III), Ph 4 P[BrIn(SPh) 3 ]|accessdate=2021-05-17|author=Raj K. Chadha, Peter C. Hayes, Hassan E. Mabrouk, Dennis G. Tuck}}</ref> ==参考文献== {{reflist}} [[Category:碘化物]] [[Category:四乙基铵盐]]
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