查看“︁四(1-降冰片烷基)钴”︁的源代码

{{Chembox
| ImageFile      = Tetrakis(1-norbornyl)cobalt(IV).png
| OtherNames     = (''T''-4)-Tetrakis(bicyclo[2.2.1]hept-1-yl)cobalt
| Section1       = {{Chembox Identifiers
| CASNo=36333-80-9
| CASNo_Ref= {{cascite|correct|CAS}}
| SMILES = C1CC2CCC1(C2)[Co](C(CC1)2CCC1C2)(C(CC1)2CCC1C2)C(CC1)2CCC1C2
| StdInChI=1S/4C7H11.Co/c4*1-2-7-4-3-6(1)5-7;/h4*6H,1-5H2;
| StdInChIKey=FULAMMPKLQBENQ-UHFFFAOYSA-N
}}
| Section2       = {{Chembox Properties
|C=28|H=44|Co=1
|Appearance = 褐色晶体
|MeltingPt = 100 °C （分解）
|SolubleOther = 可溶于THF
}}
}}
'''四(1-降冰片烷基)钴'''是一种对空气敏感的[[有机钴化合物]]，化学式为C<sub>28</sub>H<sub>44</sub>Co，可简写为Co(nor)<sub>4</sub>。它最初由Barton K. Bower和Howard G. Tennent在1972年发现。<ref name="Mnor4">{{Cite journal |last=B. K. Bower and H. G. Tennent |year=1972 |title=Transition metal bicyclo[2.2.1]hept-1-yls |journal=[[J. Am. Chem. Soc.]] |volume=94 |issue=7 |pages=2512–2514 |doi=10.1021/ja00762a056}}</ref>

它可由CoCl<sub>2</sub>·THF（或Co[CH(COCH<sub>3</sub>)<sub>2</sub>]<sub>3</sub><ref>Thiele, Karl Heinz; Dimitrov, Vladimir; Schenke, Detlef; Krueger, Annekatrin; Rusina, Albert. 1-Norbornyl compounds of tetravalent 3d transition metals. ''Wissenschaftliche Zeitschrift der Technischen Hochschule Carl Schorlemmer Leuna-Merseburg''{{de}}, 1986. 28 (2): 197-202. {{issn|0323-5270}}.</ref>）和1-降冰片烷基锂（norLi）在[[正戊烷]]中反应制得。<ref name="Mnor4"/>

:<chem>{2CoCl2.THF} + 4 norLi ->[\text{pentane}][] {[Co(nor)4]} + {Co} + 4 {LiCl} + 2 THF </chem>

:[[File:1-nobornyl-group.png|180x180px|The 1-norbornyl group]]

它可通过[[重结晶]]来提纯。

== 参考文献 ==
<references />

==外部链接==
* {{cite web |last1=Bower |first1=Barton K. |title=Tetra(bicycloheptyl) transition metal compounds |url=https://patents.google.com/patent/US3705916 |date=12 December 1972 |access-date=2022-10-31 |archive-date=2022-10-31 |archive-url=https://web.archive.org/web/20221031113156/https://patents.google.com/patent/US3705916 |dead-url=no }}

{{钴化合物}}
[[Category:降冰片烷基化合物]]
[[Category:有机钴化合物]]