查看“︁六氟锑酸铵”︁的源代码

{{Chembox
| Name = 六氟锑酸铵
| NameEn = Ammonium hexafluoroantimonate
| OtherNames = 六氟合锑(V)酸铵
| ImageFile = Ammonium hexafluoro-antimonate3D.png
| Section1 = {{Chembox Identifiers
|  CASNo = 16940-85-5
|  CASNo_Ref = {{cascite|correct|CAS}}
| SMILES = [NH4+].F[Sb-](F)(F)(F)(F)F
}}
| Section2 = {{Chembox Properties
|  Formula = NH<sub>4</sub>SbF<sub>6</sub>
|  MolarMass = 253.787
|  Appearance = 
|  Density = 
|  Solubility =  
|  MeltingPt = 
}}
}}
'''六氟锑酸铵'''是一种[[无机化合物]]，化学式为NH<sub>4</sub>SbF<sub>6</sub>。它可用于精细化学和有机合成，如用作催化剂，可以替代有机氟化物。它可溶于水。<ref>[http://www.taiwantrade.com.tw/MAIN/en_front/searchserv.do?method=listProductProductDetail&catalog_id=429411&come_soon=0 Taiwan Trade]{{Dead link|date=2018年8月 |bot=InternetArchiveBot |fix-attempted=yes }}</ref>可以形成针状或柱状的结晶。<ref>[https://books.google.com.br/books?id=FBhDAAAAIAAJ&q=NH4SbF6&dq=NH4SbF6&hl=en&sa=X&redir_esc=y Antimony: Its History, Chemistry, Mineralogy, Geology, Metallurgy, Uses, Preparations, Analysis, Production, and Valuation; with Complete Bibliographies. For Students, Manufacturers, and Users of Antimony] {{Wayback|url=https://books.google.com.br/books?id=FBhDAAAAIAAJ&q=NH4SbF6&dq=NH4SbF6&hl=en&sa=X&redir_esc=y |date=20160304230402 }}, Ch'ung-yu Wang</ref>

== 制备==
六氟锑酸铵可由[[六氟锰(IV)酸铵]]和[[五氟化锑]]反应得到：
:<math>\mathrm{4 \;SbF_5 + 2\;(NH_4)_2MnF_6 \longrightarrow 4\;NH_4SbF_6 + 2\;MnF_3 + F_2 \uparrow}</math>

五氟化锑和氟化铵的反应亦能生成六氟锑酸铵：
:<math>\mathrm{4 \;SbF_5 + NH_4F \longrightarrow NH_4SbF_6}</math>

全氟衍生物可以按下式得到：
<ref>{{Cite web |url=https://books.google.com.br/books?id=qxRhA3MZg6AC&pg=PA162&dq=NH4SbF6&hl=en&sa=X&redir_esc=y#v=onepage&q&f=false |title=Advanced Inorganic Chemistry |accessdate=2018-04-02 |archive-date=2016-04-08 |archive-url=https://web.archive.org/web/20160408005539/https://books.google.com.br/books?id=qxRhA3MZg6AC&pg=PA162&dq=NH4SbF6&hl=en&sa=X&redir_esc=y#v=onepage&q&f=false |dead-url=no }}</ref>
:<math>\mathrm{NF_3 + F_2 + SbF_5 \xrightarrow{206^oC} {NF_4SbF_6}}</math>

== 参考文献==
{{Reflist}}
== 拓展阅读==
* [http://huajing.globalchemmade.com/product/d-30262.html Huajing] {{Wayback|url=http://huajing.globalchemmade.com/product/d-30262.html |date=20210511034819 }}
* [http://www.chemicalbook.com/ProductChemicalPropertiesCB4319591_EN.htm Chemical Book] {{Wayback|url=http://www.chemicalbook.com/ProductChemicalPropertiesCB4319591_EN.htm |date=20160305070153 }}
* [http://www.chemcd.com/product/CCD08035459.html ChemCD] {{Wayback|url=http://www.chemcd.com/product/CCD08035459.html |date=20210518045631 }}
* [http://www.chemtik.com/pro_result/716045/ ChemTik]
* [http://www.wernerblank.com/publications.htm Wernerblank] {{Wayback|url=http://www.wernerblank.com/publications.htm |date=20200121032854 }}
* [https://books.google.com.br/books?id=WCKGAwAAQBAJ&pg=PA624&lpg=PA624&dq=ammonium+hexafluoroantimonate&source=bl&ots=lkX3tPAphN&sig=KR1J0meEUm-reOdlpŬir3778TU&hl=pt-BR&sa=X&ved=0CEQQ6AEwBjgKahUKEwij4rSfjdbIAhWCGpAKHUBnDY4#v=onepage&q=ammonium%20hexafluoroantimonate&f=false Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol ...] {{Wayback|url=https://books.google.com.br/books?id=WCKGAwAAQBAJ&pg=PA624&lpg=PA624&dq=ammonium+hexafluoroantimonate&source=bl&ots=lkX3tPAphN&sig=KR1J0meEUm-reOdlp%C5%ACir3778TU&hl=pt-BR&sa=X&ved=0CEQQ6AEwBjgKahUKEwij4rSfjdbIAhWCGpAKHUBnDY4#v=onepage&q=ammonium%20hexafluoroantimonate&f=false |date=20160409071501 }}, Mark Lautens
* [http://www.chemicalbook.com/ProdSupplierGWCB1397318_EN.htm Chemical Book] {{Wayback|url=http://www.chemicalbook.com/ProdSupplierGWCB1397318_EN.htm |date=20171104174938 }}
* [https://books.google.com.br/books?id=MnKkIfJ27DkC&pg=PA260&lpg=PA260&dq=ammonium+hexafluoroantimonate&source=bl&ots=DJT8PgNHJZ&sig=5XVlb0dgeNQbUJrG0ZA0T2CUDD4&hl=pt-BR&sa=X&ved=0CD8Q6AEwBTgKahUKEwij4rSfjdbIAhWCGpAKHUBnDY4#v=onepage&q=ammonium%20hexafluoroantimonate&f=false Cumulenes in Click Reactions] {{Wayback|url=https://books.google.com.br/books?id=MnKkIfJ27DkC&pg=PA260&lpg=PA260&dq=ammonium+hexafluoroantimonate&source=bl&ots=DJT8PgNHJZ&sig=5XVlb0dgeNQbUJrG0ZA0T2CUDD4&hl=pt-BR&sa=X&ved=0CD8Q6AEwBTgKahUKEwij4rSfjdbIAhWCGpAKHUBnDY4#v=onepage&q=ammonium%20hexafluoroantimonate&f=false |date=20160407115910 }}, Henri Ulrich
{{铵盐}}

[[Category:铵盐]]
[[Category:六氟锑酸盐]]