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{{Chembox | Name = 六氟铝酸铵 |ImageFile=(NH4)3AlF6.png | IUPACName =ammonium hexafluoroaluminate | OtherNames = |Section1={{Chembox Identifiers | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 11253835 | InChI = 1/Al.6FH.3H3N/h;6*1H;3*1H3/q+3;;;;;;;;;/p-3/rAlF6.3H3N/c2-1(3,4,5,6)7;;;/h;3*1H3/q-3;;;/p+3 | InChIKey = OYHBNKHFKHBTRQ-IQDJHOCXAA | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/Al.6FH.3H3N/h;6*1H;3*1H3/q+3;;;;;;;;;/p-3 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = OYHBNKHFKHBTRQ-UHFFFAOYSA-K | CASNo_Ref = {{cascite|correct|CAS}} | CASNo = 7784-19-2 | UNII_Ref = {{fdacite|correct|FDA}} | UNII = SW274S3321 | PubChem = 24565 | EC_number = 264-415-0 | SMILES = [NH4+].[NH4+].[NH4+].F[Al-3](F)(F)(F)(F)F }} | Section2 = {{Chembox Properties | Formula = (NH<sub>4</sub>)<sub>3</sub>[AlF<sub>6</sub>] | MolarMass = 195.09 | Appearance = 白色晶體 | Density = 1.78 g/cm<sup>3</sup> 当20 °C | Solubility = | MeltingPtC = 126.1 | BoilingPtC = 239.5 | pKa = | pKb = | Viscosity = }} | Section3 = {{Chembox Structure | MolShape = | Coordination = | CrystalStruct = | Dipole = }} |Section7={{Chembox Hazards | MainHazards = 刺激性 ('''Xi''') | FlashPt = | AutoignitionPt = | NFPA-H = 2 | NFPA-F = 0 | NFPA-R = 0 | NFPA-S = | GHSPictograms = {{GHS06}} | GHSSignalWord = Danger | HPhrases = {{H-phrases|301|311|330|331}} | PPhrases = {{P-phrases|260|261|264|270|271|280|284|301+310|302+352|304+340|310|311|312|320|321|322|330|361|363|403+233|405|501}} }} | Section8 = {{Chembox Related | OtherAnions = | OtherCations = | OtherCpds = }} }} '''六氟鋁酸銨''',一種白色的[[無機化合物]],[[分子式]]為(NH<sub>4</sub>)<sub>3</sub>[AlF<sub>6</sub>],可溶於水。加热时,六氟铝酸铵分解成[[三氟化铝]],并释放[[氢氟酸]]。<ref>{{cite journal |doi=10.1021/cm991195g|title=Preparation and Characterization of Different Phases of Aluminum Trifluoride|year=2000|last1=Alonso|first1 =C.|last2=Morato|first2=A.|last3=Medina|first3=F.|last4=Guirado|first4=F. |last5=Cesteros|first5=Y.|last6=Salagre|first6=P.|last7=Sueiras|first7=J. E.|last8=Terrado|first8=R.|last9=Giralt|first9=A.|journal= Chemistry of Materials|volume=12|issue=4|pages=1148–1155}}</ref>它可用于制造[[沸石]]。<ref>{{cite journal |doi=10.1016/j.molcata.2005.03.026|title=Post-synthesis alumination of mesoporous silica SBA-15 with high framework aluminum content using ammonium hexafluoroaluminate|year=2005|last1=Kao|first1=Hsien-Ming|last2=Ting|first2=Chun-Chiang|last3=Chao|first3=Shih-Wei|journal=Journal of Molecular Catalysis A: Chemical|volume=235|issue=1–2|pages=200–208}}</ref> <chem>(NH4)3AlF6 -> AlF3 + 3NH3 ^ + 3HF ^</chem> ==參見== *[[氟硼酸铵]] *[[氟硅酸铵]] *[[六氟磷酸铵]] ==參考文獻== {{reflist}} *{{cite web|url= http://www.chemyq.com/xz/xz3/22747vcoro.htm|title= 六氟铝酸铵|publisher= 化工辭典|accessdate= 2008-04-22|archive-date= 2011-12-04|archive-url= https://web.archive.org/web/20111204214827/http://chemyq.com/xz/xz3/22747vcoro.htm|dead-url= no}} {{铵盐}} {{無機化合物小作品}} [[Category:銨鹽]] [[Category:氟铝酸盐]]
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