查看“︁六氟化镅”︁的源代码

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| OtherNames = 氟化镅(VI)
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| CASNo = 90116-77-1
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| SMILES = F[Am](F)(F)(F)(F)F
| StdInChI=1S/Am.6FH/h;6*1H/q+6;;;;;;/p-6
| StdInChIKey= MOPXCOMYGFTBPM-UHFFFAOYSA-H
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| Am=1|F=6
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|Section6={{Chembox Related
| OtherCompounds = [[六氟化铀]]<br>[[六氟化锔]]
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'''六氟化镅'''是一种金属镅和[[氟]]的无机化合物，[[化学式]]为AmF<sub>6</sub>。它是一种[[假想化合物]]。<ref>{{cite book |last1=Meyer |first1=G. |last2=Morss |first2=L. R. |title=Synthesis of Lanthanide and Actinide Compounds |date=6 December 2012 |publisher=[[Springer Science & Business Media]] |isbn=978-94-011-3758-4 |page=80 |url=https://books.google.com/books?id=z0jvCAAAQBAJ&dq=Americium+hexafluoride&pg=PA80 |access-date=29 March 2023 |language=en |archive-date=2023-06-27 |archive-url=https://web.archive.org/web/20230627164535/https://books.google.com/books?id=z0jvCAAAQBAJ&dq=Americium+hexafluoride&pg=PA80 |dead-url=no }}</ref>1990年曾尝试通过氟化[[四氟化镅]]来合成该化合物，但未成功。<ref>{{cite journal |last1= Malm |first1= J. G. |last2= Weinstock |first2= B. |last3= Weaver |first3= E. E. |title= The Preparation and Properties of NpF<sub>6</sub>; a Comparison with PuF<sub>6</sub> |journal= The Journal of Physical Chemistry |year= 1958 |volume= 62 |issue= 12 |pages= 1506–1508 |doi= 10.1021/j150570a009 }}</ref>1986年的热色谱鉴定仍然没有结论。<ref name=Seppelt>{{cite journal |last1=Seppelt |first1=Konrad |date=2015 |title=Molecular Hexafluorides |journal=Chemical Reviews |volume=115 |issue=2 |pages=1296–1306 |doi=10.1021/cr5001783|pmid=25418862 }}</ref>计算表明它可能呈扭曲八面体结构。<ref name=Seppelt/>

==合成==
有科学家提出AmF<sub>6</sub>可以通过[[二氟化氪|KrF<sub>2</sub>]]与[[三氟化镅|AmF<sub>3</sub>]]在无水HF中于313-333 K下反应以冷凝态和气态两种形式制备。<ref>{{cite book |last1=Silva |first1=R. J. |last2=Bidoglio |first2=G. |last3=Robouch |first3=P. B. |last4=Puigdomenech |first4=I. |last5=Wanner |first5=H. |last6=Rand |first6=M. H. |title=Chemical Thermodynamics of Americium |date=2 December 2012 |publisher=Newnes |isbn=978-0-444-59935-3 |page=114 |url=https://books.google.com/books?id=yK3sMN_6llAC&dq=Americium+hexafluoride&pg=PA114 |access-date=29 March 2023 |language=en |archive-date=2023-06-27 |archive-url=https://web.archive.org/web/20230627164534/https://books.google.com/books?id=yK3sMN_6llAC&dq=Americium+hexafluoride&pg=PA114 |dead-url=no }}</ref>

:<chem>AmF3 + KF2 -> AmF6 + Kr</chem><ref>{{cite book |last1=Прусаков |first1=Владимир Николаевич |title=Избранные научные труды |date=2013 |publisher=[[Rosatom]] |page=59 |url=http://elib.biblioatom.ru/text/prusakov_2013/go,58/ |access-date=29 March 2023 |language=ru |archive-date=2023-03-29 |archive-url=https://web.archive.org/web/20230329114326/http://elib.biblioatom.ru/text/prusakov_2013/go,58/ |dead-url=no }}</ref>

==参考资料==
{{Reflist}}

{{六氟化物}}
{{镅化合物}}
{{氟化物}}

[[Category:镅化合物]]
[[Category:氟化合物]]
[[Category:金属卤化物]]
[[Category:六氟化物]]
[[Category:假想化合物]]
[[Category:理论化学]]