查看“︁六叠氮合磷酸五氮”︁的源代码

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| NameEn = pentanitrogen hexaazidophosphate
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|   CASNo = 781657-70-3
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| P=1 | N=23
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| Section9       = {{Chembox Related
| OtherAnions    = [[四叠氮合硼酸五氮]]
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'''六叠氮合磷酸五氮'''是一种高能材料，化学式为N<sub>5</sub><sup>+</sup>P(N<sub>3</sub>)<sub>6</sub><sup>-</sup>，它由美国科学家Christe等人于2004年制得。首先将[[五氯化磷]]与过量[[叠氮化钠]]在-20°C的[[乙腈]]中反应制得六叠氮合磷酸钠以及[[氯化钠]]。然后将六叠氮合磷酸钠与较稳定的[[六氟合锑酸]]五氮在-64°C的液态[[二氧化硫]]中反应即可制得。<ref>{{cite journal|title=Recent Advances in the Chemistry of N5+, N5− and High-Oxygen Compounds|journal=Propellants, Explosives, Pyrotechnics|date=2007-05-31|volume=32|issue=3|pages=194–204|doi=10.1002/prep.200700020|last=Christe|first=Karl O.}}</ref>该物质不稳定，在空气中易分解，并释放出大量氮气。

:<math>\rm \ PCl_5 + 6NaN_3 \xrightarrow[-20^oC]{MeCN} Na^+[P(N_3)_6]^- + 5NaCl</math>
:<math>\rm \ Na^+[P(N_3)_6]^- + N_5^+[SbF_6]^- \xrightarrow[-64^oC]{SO_2}  N_5^+[P(N_3)_6]^- + NaSbF_6</math>

==参考资料==
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[[Category:无机氮化合物]]
[[Category:磷酸盐]]
[[Category:叠氮化合物]]
[[Category:缺少物质图片的化学品条目]]
[[Category:2000年代发现的物质]]