查看“︁五羰基铁”︁的源代码

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{{chembox
| verifiedrevid = 268699765
|   Name = 五羰基铁
|  ImageFileL1 = Fe(CO)5.svg
|   ImageSizeL1 = 150px
|   ImageNameL1 = Iron carbonyl
|   ImageFileR1 = Iron-pentacarbonyl-from-xtal-3D-balls.png
|   ImageSizeR1 = 150px
|   ImageNameR1 = Iron carbonyl
|  ImageFileL2 = Sample of iron pentacarbonyl.jpg
|   ImageSizeL2 = 98px
|   ImageNameL2 = Image
|   IUPACName =  pentacarbonyliron
|   OtherNames = Pentacarbonyl iron<br>Iron carbonyl
| Section1 = {{Chembox Identifiers
|   CASNo = 13463-40-6
|    CASNo_Ref = {{cascite|correct|CAS}}
|   PubChem =  26040
| SMILES = O=C=[Fe](=C=O)(=C=O)(=C=O)=C=O
|   UNNumber = 1994
|   RTECS = NO4900000
  }}
| Section2 = {{Chembox Properties
|   Formula = Fe(CO)<sub>5</sub>
|   MolarMass = 195.90
|   Appearance = 稻草黄色液体
|   Density = 1.45 g/cm<sup>3</sup>
|   Solubility = 不可溶
|   SolubleOther = 可溶
|    Solvent = 有机溶剂
|   MeltingPt = −20 °C
|   BoilingPt = 103 °C
  }}
| Section3 = {{Chembox Structure
|   MolShape = [[三角双锥形分子构型|三角双锥]]
|   Coordination = [[三角双锥形分子构型|三角双锥]]
|   Dipole = 0 [[德拜|D]]
  }}
| Section7 = {{Chembox Hazards
|   ExternalMSDS = [http://www.ilo.org/public/english/protection/safework/cis/products/icsc/dtasht/_icsc01/icsc0168.htm ICSC 0168]
|   MainHazards = 剧毒，易燃
|   NFPA-H = 4
|   NFPA-R = 1
|   NFPA-F = 3
 |   NFPA-O =
|   FlashPt = −15 °C
|   Autoignition = 50 °C
|   ExploLimits = 3.7–12.5%
  }}
| Section8 = {{Chembox Related
|   OtherCations = [[十二羰基三钌]]<br/>[[十二羰基三锇]]
|   OtherFunctn = [[九羰基二铁]]<br/>[[十二羰基三铁]]
|    Function = 羰基铁
|   OtherCpds = [[十羰基二锰]]<br/>[[八羰基二钴]]<br/>[[四羰基镍]]
  }}
}}
'''五羰基铁'''，铁与羰基的[[化合物]]，化学式为Fe(CO)<sub>5</sub>。

== 物理性质 ==
五羰基铁[[熔点]]在-20.3℃，[[沸点]]在103.6℃，[[临界温度]]286℃。完全[[溶解]]于[[苯]]、[[溴苯]]、[[二氯苯]]、[[汽油]]、[[四氯化萘]]、[[苯醛]]、[[丙酮]]等[[溶剂]]。

== 化学性质 ==
化学性质活泼，容易形成氢化羰基物H<sub>2</sub>Fe(CO)<sub>4</sub>等化合物。

== 用途 ==
可用于制取微纳米级羰基铁粉。

== 制备 ==
让[[一氧化碳]]和铁在500℃、18MPa的高温高压的环境下，可以产生五羰基铁<ref>Brauer, Georg (1963). Handbook of Preparative Inorganic Chemistry. 2 (2nd ed.). Newyork: Academic Press. pp. 1743, 1751. ISBN 9780323161299.</ref>
::<math>\mathrm{Fe} + \mathrm{5CO} \xrightarrow[18\mathrm{MPa}]{500 ^\circ\mathrm{C}} \mathrm{Fe(CO)_5}</math>

==参考资料==
{{reflist}}
{{Iron compounds}}

{{Authority control}}
[[Category:羰基铁]]
[[Category:抗爆剂]]
[[Category:剧毒化学品]]