查看“︁五羰基溴化铼”︁的源代码

{{chembox
| verifiedrevid = 407570247
| ImageFile = Bromopentacarbonylrhenium(I)-3D-balls.png
| ImageSize = 
| IUPACName =  五羰基溴化铼
| OtherNames = 溴化五羰基铼
| Section1 = {{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 14220-21-4
| PubChem = 
| SMILES = 
  }}
| Section2 = {{Chembox Properties
|   Formula = Re(CO)<sub>5</sub>Br
|   MolarMass = 406.16 g/mol
|   Appearance = 無色
|   Density = 
|   MeltingPt = 在85-90 °C昇華（0.2 mm Hg）
|   BoilingPt = 
|   SolubleOther = 可溶
|   Solvent = [[氯碳化合物]]
  }}
| Section3 = {{Chembox Hazards
|   EUClass = 有毒('''T''')
|   FlashPt = 
|   Autoignition = 
|   RPhrases = {{R23/24/25}} {{R36/37/38}}
|   SPhrases = {{S26}} {{S28}} {{S36/37/39}} {{S45}}
  }}
}}
'''五羰基溴化铼'''（分子式Re(CO)<sub>5</sub>Br）是一種[[錸]]的[[無機化合物]]。

==製備==
五羰基溴化铼可輕易及便宜地由[[十羰基二铼]]與[[溴]]的氧化反應合成出來<ref>{{cite journal | journal = [[無機合成]] | title = Pentacarbonylrhenium Halides | author = Steven P. Schmidt, William C. Trogler, Fred Basolo | volume = 28 | year = 1990 | pages = 154–159 | doi = 10.1002/9780470132593.ch42}}{{en}}</ref>：

:<math>\mathrm{Re_2(CO)_{10} + Br_2 \longrightarrow 2ReBr(CO)_5}</math>

但它最初是由三溴化錸的[[羰基化]]而製成，並生成副產品[[溴化亞銅]]<ref>{{cite journal | author = W. Hieber, Mitarbeitern, Hans Schulten | title = XXX. Mitteilung über Metallcarbonyle. Über Rhenium-Kohlenoxyd-Verbindungen | journal = Zeitschrift für anorganische und allgemeine Chemie | year = 1939 | volume = 243 | pages = 164–173 | doi = 10.1002/zaac.19392430205 | issue = 2}}{{de}}</ref>：

:<math>\mathrm{ReBr_3 + 2Cu + 5CO \longrightarrow BrRe(CO)_5 + 2CuBr}</math>

==反應==
五羰基溴化铼是合成其他錸化合物的重要物質，例如，它可與[[鋅]]及[[乙酸]]反應並製成[[五羰基氢铼]] <ref name=Urb>{{cite journal | author = Michael A. Urbancic, John R. Shapley | title = Pentacarbonylhydridorhenium | journal = [[無機合成]] | volume = 28 | pages = 165–8 | year = 1990 | doi = 10.1002/9780470132593.ch43}}{{en}}</ref>

:<math>\mathrm{Re(CO)_5Br + Zn + HO_2CCH_3 \longrightarrow} </math>
:<math>\mathrm{ReH(CO)_5 + ZnBrO_2CCH_3}</math>

==參考資料==
{{reflist}}
{{錸化合物}}

[[Category:羰基铼]]
[[Category:溴配合物]]