查看“︁五氟溴苯”︁的源代码

{{Chembox
| ImageFile = C6F5Br.png
| ImageSize = 122
| ImageAlt = 
| IUPACName = 1-溴-2,3,4,5,6-五氟苯
| NameEn = Bromoperfluorobenzene;Bromopentafluorobenzene
| OtherNames = 溴五氟苯
|Section1={{Chembox Identifiers
| CASNo = 344-04-7
| PubChem = 9578
| EC_number = 206-449-0
| UNII = S88219080S
| ChemSpiderID = 21168727
| ChEMBL = 1231233
| StdInChI=1S/C6BrF5/c7-1-2(8)4(10)6(12)5(11)3(1)9
| StdInChIKey = XEKTVXADUPBFOA-UHFFFAOYSA-N
| SMILES = C1(=C(C(=C(C(=C1F)F)Br)F)F)F
 }}
|Section2={{Chembox Properties
| C=6|Br=1|F=5 
| MolarMass =
| Appearance = 無色液體
| Density = 1.9503 g/cm<sup>3</sup>
| MeltingPtC = -31
| BoilingPtC = 137
| Solubility = 低}}
|Section3={{Chembox Hazards
| MainHazards = 
| FlashPt = 
| AutoignitionPt = 
| GHSPictograms = {{GHS07}}
| GHSSignalWord = 警告
| HPhrases = {{H-phrases|315|319|335}}
| PPhrases = {{P-phrases|261|264|271|280|302+352|304+340|305+351+338|312|321|332+313|337+313|362|403+233|405|501}}
}}
}}
'''五氟溴苯'''是一具[[分子式]]C<sub>6</sub>F<sub>5</sub>Br之[[有機氟化合物]]。 其在常溫常壓下為一可製備五氟苯基化合物的無色液體。 這些五氟苯基化合物合成方式通常由將'''五氟溴苯'''轉換為五氟苯基鋰([[實驗式]]：C<sub>6</sub>F<sub>5</sub>Li)或是五氟苯基的對應[[格氏試劑]]。 <ref name=OS>{{cite journal|title=Pentafluorophenylcopper Tetramer, A Reagent for Synthesis of Fluorinated Aromatic Compounds|authors=Allan Cairncross, William A. Sheppard, Edward Wonchoba|journal=Org. Synth.|year=1979|volume=59|pages=122|doi=10.15227/orgsyn.059.0122}}</ref>  下方即為以五氟苯基的對應[[格氏試劑]]合成[[三(五氟苯基)硼烷]]的化學反應式:<ref>Piers, W. E.; Chivers, T. “Pentafluorophenylboranes: from Obscurity to Applications”, ''Chemical Society Reviews'', 1997, '''26''', 345-354. {{DOI|10.1039/cs9972600345}}</ref>
<chem> 3C6F5MgBr + BCl3 -> (C6F5)3B +3MgBrCl</chem>

其他'''五氟溴苯'''的衍生物包括[[四(五氟苯基)硼酸鋰|LiB(C<sub>6</sub>F<sub>5</sub>)<sub>4</sub>]]、<ref>{{cite encyclopedia|title=Lithium tetra(pentafluorophenyl)borate|authors=Tanaka, Katsunori; Fukase, Koichi|encyclopedia=e-EROS Encyclopedia of Reagents for Organic Synthesis|year=2007|doi=10.1002/047084289X.rn00752}}</ref>[CuC<sub>6</sub>F<sub>5</sub>]<sub>4</sub>,<ref name=OS/>和Ni(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>(dioxane)<sub>2</sub>。<ref>{{cite journal|authors=Sanchez, G.; Momblona, F.; Sanchez, M.; Perez, J.; Lopez, G.; Casabo, J.; Molins, E.; Miravitlles, C.|title=Synthesis of Homo- and Heterobimetallic Complexes Containing the Ni(C6F5)2 Moiety. Crystal Structure of [(C<sub>6</sub>F<sub>5</sub>)<sub>2</sub>Ni(μ-SPh)<sub>2</sub>Pd(dppe)]|journal=Eur. J. Inorg. Chem. |year=1998|pages=1199-1204|doi=10.1002/(SICI)1099-0682(199808)1998:8<1199::AID-EJIC1199>3.0.CO;2-K}}</ref>

==參考資料==
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[[Category:五氟苯基化合物]]
[[Category:全卤化合物]]