查看“︁二苯基二碲”︁的源代码
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二苯基二碲
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{{chembox | Watchedfields = changed | verifiedrevid = 401811709 | ImageFile = Difenylditelluride.png | ImageAlt = Chemical structure of diphenyl ditelluride | ImageFile1 = Diphenyl-ditelluride-(P)-enantiomer-from-xtal-Mercury-3D-sf.png | ImageAlt1 = Space-filling model of the diphenyl ditelluride molecule | PIN = 1,1′-Ditellanediyldibenzene | OtherNames = Phenylditelluride<br>Diphenylditelluride |Section1={{Chembox Identifiers | SMILES = C1([Te][Te]C2=CC=CC=C2)=CC=CC=C1 | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 90943 | PubChem = 100657 | InChI = 1/C12H10Te2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10H | InChIKey = VRLFOXMNTSYGMX-UHFFFAOYAJ | SMILES1 = [Te]([Te]c1ccccc1)c2ccccc2 | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/C12H10Te2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10H | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = VRLFOXMNTSYGMX-UHFFFAOYSA-N | CASNo_Ref = {{cascite|correct|??}} | CASNo = 32294-60-3 | RTECS = }} |Section2={{Chembox Properties | Formula = C<sub>12</sub>H<sub>10</sub>Te<sub>2</sub> | MolarMass = 409.42 g/mol | Appearance = Orange powder | Density = 2.23 g/cm<sup>3</sup> | Solubility = 难溶 | Solvent = 其它 | SolubleOther = [[二氯甲烷]] | MeltingPt = {{convert|66|-|67|C|K}} | BoilingPt = 分解 }} |Section3={{Chembox Structure | Coordination = <!-- 90° at Se<br /> -->C<sub>2</sub>对称性 | Dipole = 0 [[Debye|D]] }} |Section7={{Chembox Hazards | ExternalSDS = | MainHazards = 有毒 | RPhrases = 20/21/22-36/37/38 | SPhrases = 26-36 }} |Section8={{Chembox Related | OtherCompounds = [[diphenyl disulfide|Ph<sub>2</sub>S<sub>2</sub>]],<br />[[Diphenyl diselenide|Ph<sub>2</sub>Se<sub>2</sub>]] }} }} '''二苯基二碲'''是一种[[有机化合物]],化学式为C<sub>6</sub>H<sub>5</sub>TeTeC<sub>6</sub>H<sub>5</sub>。 ==制备== 二苯基二碲可由[[苯基溴化镁]]和[[碲]]在[[乙醚]]中反应制得:<ref>{{Literatur |Autor=Nicola Petragnani, Marcello de Moura Campos |Titel=Organische Tellurverbindungen, VI Umsetzung von elementarem Tellur mit Phenylmagnesiumbromid und Phenyllithium |Sammelwerk=Chemische Berichte |Band=96 |Nummer=1 |Datum=1963 |ISSN=1099-0682 |DOI=10.1002/cber.19630960129 |Seiten=249–252 |Online=https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cber.19630960129 |Abruf=2020-11-20}}</ref> :<chem>C6H5MgBr + Te -> C6H5TeMgBr</chem> :<chem>2C6H5TeMgBr + Te -> C6H5TeTeC6H5</chem> 另一种方法是通过苯基溴化镁和[[二溴化碲]]反应来制备:<ref name="Lederer">{{Literatur |Autor=Karl Lederer |Titel=Einwirkung von Phenylmagnesiumbromid auf Tellurdihalogene |Sammelwerk=Berichte der deutschen chemischen Gesellschaft |Band=48 |Nummer=2 |Datum=1915 |ISSN=1099-0682 |DOI=10.1002/cber.19150480223 |Seiten=1345–1350 |Online=https://chemistry-europe.onlinelibrary.wiley.com/doi/abs/10.1002/cber.19150480223 |Abruf=2020-11-20}}</ref> :<chem>C6H5MgBr + TeBr2 -> C6H5TeBr + MgBr2</chem> :<chem>2 C6H5TeBr + 2 C6H5MgBr -> (C6H5)2Te2 + 2 MgBr2 + (C6H5)2</chem> ==参考文献== {{reflist}} {{苯基化合物}} [[Category:苯基化合物]] [[Category:有机碲化合物]]
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