查看“︁二氯化钌”︁的源代码

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| Name = 
| NameEn = Ruthenium dichloride
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|   CASNo = 13465-51-5
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| Section2 = {{Chembox Properties
| Ru=1 | Cl=2
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|   Appearance = 蓝黑色
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'''二氯化钌'''是一种[[无机化合物]]，化学式为RuCl<sub>2</sub>。它可由金属钌和[[氯气]]在[[一氧化碳]]的存在下反应得到，<ref>{{cite journal|journal=Journal of the American Chemical Society|volume=46|issue=2|language=en|issn=0002-7863|date=1924-02|pages=335–342|doi=10.1021/ja01667a008|url=https://pubs.acs.org/doi/abs/10.1021/ja01667a008|title=RUTHENIUM DICHLORIDE|accessdate=2021-09-26|author=Jas. Lewis Howe, James L. Howe, S. C. Ogburn}}</ref>或通过[[三氯化钌]]和[[氢气]]在[[铂|铂黑]]和[[氯化氢]]的存在下于乙醇中反应得到：<ref>Gall, H.; Lehmann, G. The preparation of salts of bi-valent ruthenlum. ''Berichte der Deutschen Chemischen Gesellschaft [Abteilung] B: Abhandlungen'', 1926. 59B: 2856-2860. {{Issn|0365-9488}}.</ref>
:<math>\mathsf{Ru + Cl_2 \ \xrightarrow{CO}\ RuCl_2 }</math>
:<math>\mathsf{2RuCl_3 + H_2 \ \xrightarrow{Pt, HCl}\ 2RuCl_2 + 2HCl }</math>
它可以进一步被氢还原为单质[[钌]]。<ref>Reymond, J. P.; Fouilloux, P. Use of carbon fabrics as support for hydrogenation catalysts usable in polyphasic reactors. ''Studies in Surface Science and Catalysis'', 2000. 130(B): 995-1000.</ref>它可以和[[芳烃]]形成配合物。<ref>{{cite journal|journal=Journal of Organometallic Chemistry|volume=208|issue=3|language=en|date=1981-03|pages=369–387|doi=10.1016/S0022-328X(00)86722-4|url=https://linkinghub.elsevier.com/retrieve/pii/S0022328X00867224|title=Synthesis of triple halide-bridged arene complexes of ruthenium(II) and osmium(II)|accessdate=2021-09-26|author=T. Arthur, T.A. Stephenson|archive-date=2018-06-26|archive-url=https://web.archive.org/web/20180626233628/https://linkinghub.elsevier.com/retrieve/pii/S0022328X00867224}}</ref>

==参考文献==
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{{钌化合物}}
{{氯化物}}

[[Category:钌化合物]]
[[Category:氯化物]]