查看“︁乙酸苯汞”︁的源代码

{{Chembox
| Verifiedfields = changed
| verifiedrevid = 464201286
| ImageFile1 = Phenylmercuric Acetate.svg
|  ImageFile1_Ref = {{Chemboximage|correct|??}}
|  ImageSize1 = 244
|  ImageName1 = 乙酸苯汞的结构
| ImageFile2 = Phenylmercury(II)-acetate-from-xtal-3D-balls.png
|  ImageFile2_Ref = {{Chemboximage|correct|??}}
|  ImageSize2 = 244
|  ImageName2 = 乙酸苯汞的球棍模型
| IUPACName = Anticon
| SystematicName =acetyloxy(phenyl)mercury
| OtherNames = 醋酸苯汞，苯基乙酸汞，赛力散原粉
| Section1 = {{Chembox Identifiers
|  InChI = 1S/C6H5.C2H4O2.Hg/c1-2-4-6-5-3-1;1-2(3)4;/h1-5H;1H3,(H,3,4);/q;;+1/p-1
|  InChIKey1 = XEBWQGVWTUSTLN-UHFFFAOYSA-M
|  CASNo = 62-38-4
|   CASNo_Ref = {{cascite|correct|CAS}}
|  PubChem = 16682730
|   PubChem_Ref = {{Pubchemcite|correct|PubChem}}
|  ChemSpiderID = 10294750
|   ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
|  UNII = OSX88361UX
|   UNII_Ref = {{fdacite|changed|FDA}}
|  EINECS = 200-532-5
|  UNNumber = 1674
|  KEGG = D05464
|   KEGG_Ref = {{keggcite|changed|kegg}}
|  MeSHName = Phenylmercuric+acetate
|  ChEBI_Ref = {{ebicite|correct|EBI}}
|  ChEBI = 27684
|  RTECS = OV6475000
|  Beilstein = 3662930
|  Gmelin = 83357
|  SMILES = CC(=O)O[Hg]C1=CC=CC=C1
|  SMILES1 = CC(=O)O[Hg]c1ccccc1
|  StdInChI = 1S/C6H5.C2H4O2.Hg/c1-2-4-6-5-3-1;1-2(3)4;/h1-5H;1H3,(H,3,4);/q;;+1/p-1
|   StdInChI_Ref = {{stdinchicite|correct|chemspider}}
|  StdInChIKey = XEBWQGVWTUSTLN-UHFFFAOYSA-M
|   StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
  }}
| Section2 = {{Chembox Properties
|  C = 8
|  H = 8
|  Hg = 1
|  O = 2
|  Appearance = 白色结晶粉末<ref name="oxford" />
|  Density = 2.58 g/cm<sup>3</sup><ref name="zghg">中国化工产品大全 上卷，Da215 醋酸苯汞，页544</ref>
|  MeltingPtCL = 148
|  MeltingPtCH = 151
|  Solubility= 微溶<ref name="oxford">[http://msds.chem.ox.ac.uk/PH/phenylmercuric_acetate.html Safety data for phenylmercuric acetate]</ref>
  }}
| Section3 = {{Chembox Hazards
|  ExternalMSDS= [http://www.chemicalbook.com/ProductMSDSDetailCB6703824.htm 中文MSDS]<br />[http://msds.chem.ox.ac.uk/PH/phenylmercuric_acetate.html Oxford MSDS]
|  EUIndex = 080-011-00-5
|  EUClass = {{Hazchem T}} {{Hazchem N}}<ref name="oxford" />
|  RPhrases = {{R25}}, {{R34}}, {{R48/24/25}}, {{R50/53}}<ref name="oxford" />
|  SPhrases = {{S1/2}}, {{S23}}, {{S24/25}}, {{S37}}, {{S45}}, {{S60}}, {{S61}}<ref name="oxford" />
|  LD50 = 30 mg/kg (大鼠经口)<ref name="zghg" /><br />39.5 mg/kg (小鼠经口)<ref name="cb1">[http://www.chemicalbook.com/ProductMSDSDetailCB6703824.htm 醋酸苯汞(62-38-4)]</ref>
  }}
}}
'''乙酸苯汞'''，又名'''醋酸苯汞'''。结构式CH<sub>3</sub>C(O)OHgC<sub>6</sub>H<sub>5</sub>。

== 性质 ==
白色至微黄色细小闪光的无嗅菱形结晶，在室温下微有挥发性。微溶于水，溶于[[乙醇]]、[[乙酸]]、[[丙酮]]、[[氯仿]]和[[苯]]，易溶于[[乙醚]]。剧毒。

== 制备 ==
由[[氧化汞]]、[[冰醋酸]]与[[苯]]在[[三氟化硼]]催化下一步反应而得。<ref>{{cite book| author=Franz v. Bruchhausen, Gerd Dannhardt, Siegfried Ebel, August-Wilhelm Frahm, Eberhard Hackenthal, Ulrike Holzgrabe | title=Hagers Handbuch der Pharmazeutischen Praxis | publication-place=Berlin, Heidelberg | date=1994 | isbn=978-3-642-57880-9 | oclc=913646713 | language=de}}</ref>

:<math>\ HgO+CH_3COOH+C_6H_6\rightarrow C_6H_5HgO(O)CCH_3+H_2O</math>

== 用途 ==
用于[[避孕药]]的生产；也在农业上用作杀虫剂，用于拌种，可防止小麦[[黑穗病]]和水稻[[稻瘟病]]等，不过在中国已不再使用。<ref name="zghg" />

== 参考资料 ==
{{reflist}}
{{汞化合物}}
[[Category:有机汞化合物]]
[[Category:芳香化合物]]
[[Category:苯基金属]]