查看“︁三苯基氯硅烷”︁的源代码

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|   MeltingPt = {{convert|90|-|92|C|K}}<ref>{{cite journal|last1=Speier|first1=John L.|last2=Zimmerman|first2=Ruth E.|title=Disproportionation of Phenylsilanes with Aluminum Chloride as the Catalyst|journal=Journal of the American Chemical Society|volume=77|issue=23|year=1955|pages=6395–6396|issn=0002-7863|doi=10.1021/ja01628a110}}</ref>
|   BoilingPt = {{convert|378|C|K}}<ref>Bochkarev, V. N.; Turetskaya, R. A.; Troitskaya, N. N.; Luskina, B. M.; Savushkina, V. I.; Korablina, T. P.; Dzvonar, V. G.; Chernysheva, N. I. High-boiling by-products from the synthesis of phenylchlorosilanes. ''Zhurnal Obshchei Khimii'', 1983. 53 (4): 824-827. ISSN: 0044-460X</ref>
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'''三苯基氯硅烷'''是一种[[有机硅化合物]]，化学式为(C<sub>6</sub>H<sub>5</sub>)<sub>3</sub>SiCl。

==制备==
三苯基氯硅烷最初于1886年由A. Polis用[[五氯化磷]]和[[四苯基硅烷]]按化学计量比反应得到：<ref>A. Polis: Ueber aromatische Siliciumverbindungen{{de}}. In: Berichte der deutschen chemischen Gesellschaft. Band 19, Nr. 1, Januar 1886, S. 1012–1024,</ref>
:<math>\mathrm{Si(C_6H_5)_4 \ + PCl_5 \longrightarrow Si(C_6H_5)_3Cl + \ Cl{-}C_6H_5 \ + \ PCl_3}</math>
它也可由[[苯基氯化镁]]和[[四氯化硅]]反应得到：
:<math>\mathrm{3 \ ClMgC_6H_5 + SiCl_4 \longrightarrow Si(C_6H_5)_3Cl + \ 3 \ MgCl_2}</math>

==性质==
三苯基氯硅烷可以和[[5-溴-1,3-苯二酚]]在[[二氯甲烷]]中反应，得到5-溴-1,3-二(三苯基硅氧基)苯。<ref>{{cite journal|last1=Pekarek|first1=Ryan T.|last2=Celio|first2=Hugo|last3=Rose|first3=Michael J.|title=Synthetic Insights into Surface Functionalization of Si(111)–R Photoelectrodes: Steric Control and Deprotection of Molecular Passivating Layers|journal=Langmuir|volume=34|issue=22|year=2018|pages=6328–6337|issn=0743-7463|doi=10.1021/acs.langmuir.7b03564}}</ref>

==另见==
* [[氯化三苯基锡]]

==参考文献==
{{reflist}}
{{矽化合物}}
[[Category:有机硅化合物]]
[[Category:硅-氯化合物]]