查看“︁三甲基氢化锗”︁的源代码

{{Chembox
|ImageFile=Trimethylgermane.svg
|OtherNames=三甲基锗烷
|Section1={{Chembox Identifiers
| CASNo= 1449-63-4
| PubChem         = 207193933
|SMILES=C[GeH](C)C
}}
|Section2={{Chembox Properties
|C=3|H=10|Ge=1
| Appearance= 无色清澈液体<ref name="Gelest_neu" />
| Density= 1,01 g·cm<sup>−3</sup><ref name="ChemicalBook" />
| MeltingPt= −123 °C<ref name="Jane E. Macintyre">{{cite book | title=Dictionary of organometallic compounds | url=https://archive.org/details/dictionaryoforga0001unse_x8u1 | publisher=Chapman and Hall | publication-place=London New York | year=1995 | isbn=978-0-412-43060-2 | oclc=31763519 | ref={{sfnref | Chapman and Hall | 1995}}}}</ref><ref name="Gelest_neu" />
| BoilingPt= 26–27 °C<ref name="ChemicalBook" />
| Solubility= 不溶<ref name="Gelest_neu" />
}}
}}

'''三甲基氢化锗'''是一种[[有机锗化合物]]，化学式 (CH<sub>3</sub>)<sub>3</sub>GeH。

==制备 ==
三甲基氢化锗可以由[[三甲基溴化锗]]在[[苯]]中被[[氢化铝锂]]还原而成：<ref name="JPhysChem1973" />
: <math>\mathrm{4 \ BrGe(CH_3)_3 + \ LiAlH_4 \xrightarrow[C_6H_6]{-5\, {}^{\circ}C}\ 4 \ HGe(CH_3)_3 \ + \ LiBr \ + \ AlBr_3 }</math>

== 性质==
三甲基氢化锗是无色清澈液体，闪点低于 −20 °C。<ref name="Gelest_neu" /><ref name="ChemicalBook" />

它和[[叔丁基锂]]在[[四氢呋喃|THF]]里反应，可以得到对应的锂盐：<ref name="Organometallics" />
: <math>\mathrm{\ HGe(CH_3)_3 + \ LiC(CH_3)_3 \ \xrightarrow[THF]{-10\, {}^{\circ}C}\  LiGe(CH_3)_3 \ + \ C_4H_{10} }</math>

== 参考资料==
<references>
<ref name="ChemicalBook">
{{ChemicalBook|1=7740918|2=TRIMETHYLGERMANE|3=2015-04-19}}
</ref>
<ref name="Gelest_neu">{{Internetquelle |url=http://www.gelest.com/wp-content/uploads/GET8560_TRIMETHYLGERMANE_GHS-US_English-US.pdf |titel=TRIMETHYLGERMANE, Safety Data Sheet GET8560 |hrsg=GELEST, INC. |datum=2016-01-25 |zugriff=2019-12-27 |format=PDF |sprache=en }} {{Wayback|url=http://www.gelest.com/wp-content/uploads/GET8560_TRIMETHYLGERMANE_GHS-US_English-US.pdf |date=20161101095706 }} {{Cite web |url=http://www.gelest.com/wp-content/uploads/GET8560_TRIMETHYLGERMANE_GHS-US_English-US.pdf |title=存档副本 |access-date=2022-03-13 |archive-date=2016-11-01 |archive-url=https://web.archive.org/web/20161101095706/http://www.gelest.com/wp-content/uploads/GET8560_TRIMETHYLGERMANE_GHS-US_English-US.pdf |dead-url=unfit }}</ref>
<ref name="JPhysChem1973">
{{cite journal | last=Durig | first=J. R. | last2=Chen | first2=M. M. | last3=Li | first3=Y. S. | last4=Turner | first4=J. B. | title=Spectra and structure of organogermanes. XV. Microwave spectrum of trimethylgermane | journal=The Journal of Physical Chemistry | publisher=American Chemical Society (ACS) | volume=77 | issue=2 | year=1973 | issn=0022-3654 | doi=10.1021/j100621a016 | pages=227–229}}
</ref>
<ref name="Organometallics">
{{cite journal | last=Piers | first=Edward | last2=Lemieux | first2=Rene | title=Reaction of (Trimethylgermyl)copper(I)-Dimethyl Sulfide with Acyl Chlorides: Efficient Syntheses of Functionalized Acyltrimethylgermanes | journal=Organometallics | publisher=American Chemical Society (ACS) | volume=14 | issue=11 | year=1995 | issn=0276-7333 | doi=10.1021/om00011a016 | pages=5011–5012}}
</ref>
</references>
{{锗化合物}}

[[Category:三甲基锗基化合物]]