查看“︁三氯溴甲烷”︁的源代码

{{Chembox
| Name = 
| NameEn = Bromotrichloromethane
| ImageFile = Bromotrichloromethane_FormulaV1.svg
|  ImageSize = 150px
|  ImageAlt = 
| IUPACName = 
| IUPACNameZh = 
| OtherNames = 溴三氯甲烷
| Section1 = {{Chembox Identifiers
|   CASNo = 75-62-7
|   CASNo_Ref = {{cascite|correct|CAS}}
|   PubChem = 
|   SMILES =  }}
| Section2 = {{Chembox Properties
| C=1 | Br=1 | Cl=3
|   Appearance = 有刺激性气味的无色液体
|   Density = 2.012 g·cm<sup>−3</sup>（25 °C）<ref name=nlm>"Hazardous Substances Data Bank" data were obtained from the National Library of Medicine (US). Retrieved from SciFinder. [2021-11-01].</ref>
|   MeltingPt = −5.7 °C<ref name=nlm />
|   BoilingPt = 105 °C<ref name=nlm />
|   Solubility =  }}
| Section3 = {{Chembox Hazards
|   MainHazards = 
|   FlashPt = 
|   Autoignition =  }}
}}
'''三氯溴甲烷'''是一种[[有机化合物]]，化学式为CBrCl<sub>3</sub>，它是无色的挥发性液体。

==制备和反应==

三氯溴甲烷可由[[三氯乙酸钾]]和[[溴]]在120 °C反应得到。<ref>{{cite book | last=Katritzky | first=A.R. | last2=Gilchrist | first2=T.L. | last3=Meth-Cohn | first3=O. | last4=Rees | first4=C.W. | title=Comprehensive Organic Functional Group Transformations | publisher=Elsevier Science | series=Comprehensive Organic Functional Group Transformations | issue=Bd. 6 | year=1995 | isbn=978-0-08-042704-1 | url=https://books.google.de/books?id=YzBveZGm0GEC&pg=PA221 | access-date=2021-11-01 | page=221 | archive-date=2021-11-04 | archive-url=https://web.archive.org/web/20211104192910/https://books.google.de/books?id=YzBveZGm0GEC&pg=PA221 }}</ref>
:<math>\mathrm{Cl_3CCO_2K + Br_2 \longrightarrow CBrCl_3 + CO_2 + KBr}</math>
[[三氯甲烷]]和[[一氯化溴]]在[[氟三氯甲烷]]中的光化学反应可以得到三氯溴甲烷，副产物是[[四氯化碳]]。<ref>{{cite journal|journal=Tetrahedron Letters|volume=27|issue=43|language=en|date=1986-01|pages=5181–5184|doi=10.1016/S0040-4039(00)85163-1|url=https://linkinghub.elsevier.com/retrieve/pii/S0040403900851631|title=Reactions of BrCl with alkyl radicals.|accessdate=2021-11-01|author=P.S Skell, H.N Baxter, J.M Tanko|archive-date=2018-07-02|archive-url=https://web.archive.org/web/20180702225218/https://linkinghub.elsevier.com/retrieve/pii/S0040403900851631}}</ref>[[四氯化碳]]和[[三溴化铝]]反应也会生成该化合物，副产物是[[二氯二溴甲烷]]。<ref>{{cite journal|journal=Journal für Praktische Chemie|volume=22|issue=5-6|language=en|date=1963-12|pages=230–231|doi=10.1002/prac.19630220503|url=https://onlinelibrary.wiley.com/doi/10.1002/prac.19630220503|title=Eine Einfache Darstellungsmethode für Bromtrichlormethan|accessdate=2021-11-01|author=Gerhard Lehmann, Bernhard Lücke|archive-date=2021-11-01|archive-url=https://web.archive.org/web/20211101180458/https://onlinelibrary.wiley.com/doi/10.1002/prac.19630220503}}</ref>

它和[1.1.1][[螺桨烷]]反应，可以得到1-三氯甲基-3-溴双环[1.1.1]戊烷。<ref>{{cite journal|journal=Journal of the American Chemical Society|volume=112|issue=6|language=en|issn=0002-7863|date=1990-03|pages=2194–2216|doi=10.1021/ja00162a022|url=https://pubs.acs.org/doi/abs/10.1021/ja00162a022|title=Reactions of [1.1.1]propellane|accessdate=2021-11-01|author=Kenneth B. Wiberg, Sherman T. Waddell|archive-date=2021-11-02|archive-url=https://web.archive.org/web/20211102041123/https://pubs.acs.org/doi/abs/10.1021/ja00162a022}}</ref>在催化下，它可以和[[苯乙烯]]反应，得到1-溴-3,3,3-三氯丙基苯。<ref>{{cite journal|journal=Tetrahedron Letters|volume=51|issue=5|language=en|date=2010-02|pages=822–825|doi=10.1016/j.tetlet.2009.12.011|url=https://linkinghub.elsevier.com/retrieve/pii/S0040403909022874|title=Cycloruthenated complexes as homogeneous catalysts for atom-transfer radical additions|accessdate=2021-11-01|author=Ksenia Parkhomenko, Laurent Barloy, Jean-Baptiste Sortais, Jean-Pierre Djukic, Michel Pfeffer|archive-date=2018-06-02|archive-url=https://web.archive.org/web/20180602212233/https://linkinghub.elsevier.com/retrieve/pii/S0040403909022874}}</ref>
==参考文献==
{{reflist}}

{{卤代甲烷}}

[[Category:氯代烷烃]]
[[Category:溴代烷烃]]
[[Category:卤代甲烷]]