查看“︁三氟氯乙烯”︁的源代码
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三氟氯乙烯
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{{Chembox | Watchedfields = changed | verifiedrevid = 414432719 | ImageFileL1_Ref = {{chemboximage|correct|??}} | ImageFileL1 = Chlortrifluorethen.svg | ImageNameL1 = Structural formula of chlorotrifluoroethylene | ImageFileR1 = Chlorotrifluoroethene-3D-balls.png | ImageNameR1 = Ball-and-stick model of chlorotrifluoroethylene | IUPACName = 1-Chloro-1,2,2-trifluoroethene | OtherNames = | Reference = <ref name="hand"> {{cite book | last = Lide | first = David R. | year = 1998 | title = Handbook of Chemistry and Physics | url = https://archive.org/details/isbn_9780849305948 | edition = 87 | volume = | location = Boca Raton, Florida | publisher = CRC Press | isbn = 0-8493-0594-2 | pages = [https://archive.org/details/isbn_9780849305948/page/3 3]–126}}</ref> |Section1={{Chembox Identifiers | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 6345 | InChI = 1/C2ClF3/c3-1(4)2(5)6 | InChIKey = UUAGAQFQZIEFAH-UHFFFAOYAH | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/C2ClF3/c3-1(4)2(5)6 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = UUAGAQFQZIEFAH-UHFFFAOYSA-N | CASNo_Ref = {{cascite|correct|CAS}} | CASNo = 79-38-9 | PubChem = 6594 | SMILES = F/C(F)=C(/Cl)F }} |Section2={{Chembox Properties | C=2 | F=3 | Cl=1 | Appearance = 无色气体 | Odor = 弱的[[乙醚]]味 | Density = 1.54 g/cm<sup>3</sup> at −60°C | MeltingPtC = -158.2 | BoilingPtC = -27.8 | Solubility = 4.01 g/100 mL | SolubleOther = 可溶于[[苯]]、[[氯仿]] | RefractIndex = 1.38 (0 °C) | MagSus = -49.1·10<sup>−6</sup> cm<sup>3</sup>/mol }} |Section3={{Chembox Hazards | MainHazards = | NFPA-H = 3 | NFPA-F = 4 | NFPA-R = 3 | FlashPt = | AutoignitionPt = | ExploLimits = 24-40.3% }} |Section8={{Chembox Related | OtherAnions = | OtherCations = | OtherCompounds = [[四氟乙烯]]<BR>[[三氟溴乙烯]]<BR>[[四氯乙烯]] }} }} '''三氟氯乙烯'''(Trifluorochloroethylene),别名'''氯三氟乙烯''',结构式CF<sub>2</sub>=CFCl。 ==性质== *在水中分解,易聚合。 *临界温度:105.3 °C *临界压力:4.063 MPa *剧毒。在空气中易变质产生[[光气]]。{{citation needed}} *[[LD50|LD<sub>50</sub>]]:268 mg/kg(大鼠经口) ==制备和反应== 由[[1,1,2-三氟-1,2,2-三氯乙烷]]与[[锌]]粉在[[甲醇]]介质中作用发生脱氯得到,经分馏提纯制得成品。 :<math>\ CF_2ClCFCl_2+Zn\rightarrow CF_2\!=\!CFCl+ZnCl_2</math> 三氟氯乙烯的热二聚会得到1,2-二氯-1,2,3,3,4,4-六氟环丁烷。<ref>{{cite journal |doi=10.1039/JR9520003830|title=The High-Temperature Dimerisation of Chlorotrifluoroethylene|year=1952|last1=Buxton|first1=M. W.|last2=Ingram|first2=D. W.|last3=Smith|first3=F.|last4=Stacey|first4=M.|last5=Tatlow|first5=J. C.|journal=Journal of the Chemical Society (Resumed)|page=3830}}</ref>将此化合物脱氯可得[[六氟环丁烯]]。 ==用途== 用于生产[[聚三氟氯乙烯]]、氟橡胶、氟塑料、氟氯润滑油和吸入麻醉剂等。 ==参考资料== {{refs}} [[Category:烯烃]] [[Category:全卤化合物|乙]] [[Category:氯氟烃]] [[Category:二碳有机物]] [[Category:三氟乙烯基化合物]]
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