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{{Chembox | Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 403672360 | ImageFile = Butyryl chloride.png | ImageSize = 150px | ImageFile1 = Butyryl-chloride-3D-balls.png | ImageName1 = Ball-and-stick model | IUPACName= Butanoyl chloride | OtherNames = 正丁酰氯 |Section1={{Chembox Identifiers | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/C4H7ClO/c1-2-3-4(5)6/h2-3H2,1H3 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = DVECBJCOGJRVPX-UHFFFAOYSA-N | CASNo_Ref = {{cascite|correct|CAS}} | CASNo = 141-75-3 | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 8523 | EC_number = 205-498-5 | PubChem = 8855 | UNNumber = 2353 | UNII = 2XVM8E16IR | ChEMBL = 1300263 | InChI = 1/C4H7ClO/c1-2-3-4(5)6/h2-3H2,1H3 | InChIKey = DVECBJCOGJRVPX-UHFFFAOYAA | SMILES=ClC(=O)CCC | MeSHName=}} |Section2={{Chembox Properties |C=4|H=7|Cl=1|O=1 | Appearance=无色液体<ref name="GESTIS">{{GESTIS|Name=Butyrylchlorid|ZVG=510535|CAS=141-75-3|Abruf=2016-07-23}}</ref> | Odor = 泼辣 | Density= 1.03 g/cm<sup>3</sup><ref name="GESTIS" /> | MeltingPtC =-89 | BoilingPtC =101 |Melting_notes=<ref name="GESTIS" /> |Boiling_notes=<ref name="GESTIS" /> | Solubility = 分解<ref name="GESTIS" /> | SolubleOther = 混溶于[[乙醚]]<br />混溶于[[乙醇]]<ref name="David R. Lide, Ph.D., Thomas J. Bruno">{{cite book| editor= David R. Lide | title= CRC Handbook of Chemistry and Physics 2012-2013 | publisher= CRC Press | ISBN = 1439880492 | date= 2012 | page = 3-78 }}</ref> | RefractIndex = 1.412 | MagSus = -62.1·10<sup>−6</sup> cm<sup>3</sup>/mol }} |Section3={{Chembox Hazards | FlashPtC = 21.7 | MainHazards = 和水剧烈反应,可燃,腐蚀性 | GHSPictograms = {{GHS02}}{{GHS05}} | GHSSignalWord = Danger | HPhrases = {{H-phrases|225|314}} | PPhrases = {{P-phrases|210|233|240|241|242|243|260|264|280|301+330+331|303+361+353|304+340|305+351+338|310|321|363|370+378|403+235|405|501}} | NFPA-F = 3 | NFPA-H = 3 | NFPA-R = 2 }} }} '''丁酰氯'''是一种[[有机化合物]],[[化学式]] CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>C(O)Cl.它是一种有泼辣气味的无色液体。丁酰氯可溶于非质子有机溶剂,但易与水和醇反应。它通常由[[丁酸]]的氯化而成。<ref>{{cite journal|title=n-Butyryl Chloride|first1= B. |last1=Helferich|first2=W.|last2=Schaefer|journal= Org. Synth. |year=1929|volume=9|page=32|doi=10.15227/orgsyn.009.0032}}</ref> == 制备 == 丁酰氯可以由[[丁酸]]和[[氯化亚砜]]反应而成。<ref name="V.K. Ahluwalia, R. Aggarwal">{{cite book| author= V. K. Ahluwalia, R. Aggarwal | title= Comprehensive Practical Organic Chemistry: Preparations And Quantitative Analysis | publisher= University Press (India) | ISBN = 8173714754 | date= 2000 |page= 15 }}</ref> :<math>\mathrm{C_4H_7OOH + SOCl_2 \longrightarrow C_4H_7ClO + SO_2 + HCl}</math> == 用处== 丁酰氯在有机化学中可用于傅-克反应。<ref name="Hisashi Yamamoto, Koichiro Oshima">{{cite book| author= Hisashi Yamamoto, Koichiro Oshima | title= Main Group Metals in Organic Synthesis | publisher= John Wiley & Sons | ISBN = 9783527605354 | date= 2006 | page= 370 }}</ref> 丁酰氯的衍生物克用于制造农药、药物、香水固定剂、聚合催化剂和染料。丁酰氯也常用作有机合成的中间体,用于制备[[药物]]、[[农用化学品]]、染料、[[酯]]和过氧化物。<ref>{{Cite web |url=http://chemicalland21.com/specialtychem/perchem/N-BUTYRYL%20CHLORIDE.htm |title=存档副本 |access-date=2021-08-05 |archive-date=2010-01-14 |archive-url=https://web.archive.org/web/20100114210018/http://chemicalland21.com/specialtychem/perchem/N-BUTYRYL%20CHLORIDE.htm }}</ref> ==危险性== 丁酰氯和空气形成爆炸性混合物。<ref name="GESTIS" /> ==参考资料== {{reflist}} {{酰卤}} [[Category:酰氯]]
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