查看“︁一硒化钚”︁的源代码

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| OtherNames = 硒化钚(II)
|Section1={{Chembox Identifiers
| CASNo = 23299-88-9
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|Section2={{Chembox Properties
|Pu=1|Se=1
| Appearance = 黑色晶体
| Density = 
| MeltingPtC = 2075
| BoilingPtC = 
| Solubility = 难溶}}
|Section3={{Chembox Hazards
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| GHSSignalWord = 警告
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|Section6={{Chembox Related
| OtherCpds = [[二硒化钚]]<br>[[一硫化钚]]
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'''一硒化钚'''是一种[[无机化合物]]，化学式为PuSe，它可以形成黑色晶体，难溶于水。<ref>{{cite book |last1=Eyring |first1=LeRoy |last2=O'Keeffe |first2=Michael |title=The Chemistry of Extended Defects in Non-metallic Solids: Proceedings of the Institute for Advanced Study on the Chemistry of Extended Defects in Non-Metallic Solids, Casa Blanca Inn, Scottsdale, Arizona, April 16-26, 1969 |date=1970 |publisher=[[North-Holland Publishing Company]] |isbn=978-0-7204-0164-6 |page=140 |url=https://www.google.ru/books/edition/The_Chemistry_of_Extended_Defects_in_Non/WtHQAAAAMAAJ?hl=en&gbpv=1&bsq=Plutonium+selenide&dq=Plutonium+selenide&printsec=frontcover |access-date=6 August 2021 |language=en}}</ref><ref>{{cite book |last1=Burke |first1=Robert |title=Hazardous Materials Chemistry for Emergency Responders |date=17 June 2013 |publisher=[[CRC Press]] |isbn=978-1-4398-4986-6 |page=85 |url=https://books.google.com/books?id=XHfRBQAAQBAJ&q=plutonium+selenide&pg=PA85 |access-date=6 August 2021 |language=en |archive-date=2022-05-10 |archive-url=https://web.archive.org/web/20220510081006/https://books.google.com/books?id=XHfRBQAAQBAJ&q=plutonium+selenide&pg=PA85 }}</ref>它可由[[三硒化二钚]]和[[三氢化钚]]反应得到，或由[[化学计量比]]的单质化合得到：
::<math>\mathsf{  2 Pu_2Se_3 + 2 PuH_3 \ \xrightarrow{1600^oC}\ 4 PuSe + 3 H_2 }</math>
::<math>\mathsf{ Pu + Se \ \xrightarrow{220-1000^oC}\ PuSe }</math>

一硒化钚是[[立方晶系]]晶体，空间群Fm{{overline|3}}m，晶胞参数a = 0.57934 nm，Z = 4，有NaCl结构。<ref>{{cite web |title=WebElements Periodic Table » Plutonium » plutonium selenide |url=https://www.webelements.com/compounds/plutonium/plutonium_selenide.html |publisher=webelements.com |access-date=6 August 2021 |archive-date=2021-12-25 |archive-url=https://web.archive.org/web/20211225073025/https://www.webelements.com/compounds/plutonium/plutonium_selenide.html }}</ref>它在高压下发生相变，在20 GPa形成三方相，35 GPa形成立方CsCl相。<ref>{{cite journal |last1=Gensini |first1=M. |last2=Gering |first2=E. |last3=Heathman |first3=S. |last4=Benedict |first4=U. |last5=Spirlet |first5=J. C. |title=High-pressure phases of plutonium monoselenide studied by X-ray diffraction |journal=High Pressure Research |date=1 April 1990 |volume=2 |issue=5–6 |pages=347–359 |doi=10.1080/08957959008203187 |url=https://www.tandfonline.com/doi/abs/10.1080/08957959008203187?journalCode=ghpr20 |access-date=6 August 2021 |issn=0895-7959 |archive-date=2022-01-18 |archive-url=https://web.archive.org/web/20220118014743/https://www.tandfonline.com/doi/abs/10.1080/08957959008203187?journalCode=ghpr20 }}</ref>其[[磁化率]]遵循[[居里-外斯定律]]。<ref>{{cite book |last1=Macintyre |first1=Jane E. |title=Dictionary of Inorganic Compounds |date=23 July 1992 |publisher=[[CRC Press]] |isbn=978-0-412-30120-9 |page=3783 |url=https://books.google.com/books?id=9eJvoNCSCRMC&q=plutonium+selenide&pg=PA3783 |access-date=6 August 2021 |language=en |archive-date=2022-03-26 |archive-url=https://web.archive.org/web/20220326132124/https://books.google.com/books?id=9eJvoNCSCRMC&q=plutonium+selenide&pg=PA3783 }}</ref>

==参考文献==
{{Reflist}}

==拓展阅读==
* {{cite journal|journal=Journal of the Korean Physical Society|volume=63|issue=3|language=en|issn=0374-4884|date=2013-08|pages=809–811|doi=10.3938/jkps.63.809|url=http://link.springer.com/10.3938/jkps.63.809|title=Electronic structures of of PuX (X=S, Se, Te)|accessdate=2021-08-08|author=Takahiro Maehira, Eijiro Sakai, Yasutomi Tatetsu}}
* {{cite journal|journal=Science|volume=335|issue=6075|language=en|issn=0036-8075|date=2012-03-23|pages=1464–1466|doi=10.1126/science.1216184|url=https://www.sciencemag.org/lookup/doi/10.1126/science.1216184|title=Actinide Topological Insulator Materials with Strong Interaction|accessdate=2021-08-08|author=X. Zhang, H. Zhang, J. Wang, C. Felser, S.-C. Zhang}}

{{钚化合物}}
{{硒化物}}

[[Category:钚化合物]]
[[Category:硒化物]]