查看“︁一氮化锆”︁的源代码

{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 402916257
| NameEn = Zirconium nitride
| ImageFile = ZrN-polyhedral.png
| ImageSize = 160px
| ImageName = Zirconium nitride in the unit cell
| IUPACName = Zirconium nitride
| OtherNames = 氮化锆(III)<br>氮化锆
|Section1={{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo = 25658-42-8
| PubChem = 94359
| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}
| ChemSpiderID = 85159
| SMILES = N#[Zr]
| SMILES_Comment = (Zr≡N)
| StdInChI_Ref = {{stdinchicite|changed|chemspider}}
| StdInChI = 1S/N.Zr
| StdInChI_Comment = (Zr≡N)
| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}}
| StdInChIKey = ZVWKZXLXHLZXLS-UHFFFAOYSA-N
| EC_number = 247-166-2
  }}
|Section2={{Chembox Properties
| Formula = ZrN<ref name=crc>{{CRC90}}</ref>
| Appearance = 黄棕色晶体
| Odor = 无
| Density = 7.09 g/cm<sup>3</sup> (24&nbsp;°C)<ref name=crc>{{CRC90}}</ref>
| MeltingPtC = 2952
| MeltingPt_notes = <br> at 760 mmHg<ref name=crc />
| BoilingPtC =
| Solubility = 不溶
| SolubleOther = 可溶于浓[[氢氟酸|HF]]<ref name=crc />
  }}
|Section3={{Chembox Structure
| CrystalStruct = [[立方晶系]]，[[皮尔逊符号|cF8]]<ref name=aip>{{Cite journal | doi = 10.1063/1.4879798| title = FP-LAPW investigation of electronic, magnetic, elastic and thermal properties of Fe-doped zirconium nitride| journal = AIP Advances| volume = 4| issue = 5| pages = 057121| year = 2014| last1 = Sirajuddeen | first1 = M. Md. Sheik. | last2 = Banu | first2 = I. B. S. | doi-access = free}}</ref>
| SpaceGroup = Fm{{overline|3}}m, No. 225<ref name=aip />
| Coordination = 八面体型<ref name=aip />
| LattConst_a = 4.5675&nbsp;Å<ref name=aip />
| LattConst_b = 
| LattConst_c = 
| LattConst_alpha = 90
| LattConst_beta = 90
| LattConst_gamma = 90
  }}
|Section4={{Chembox Thermochemistry
| DeltaHf = −365.26 kJ/mol<ref name=nist>{{nist|name=Zirconium nitride|id=C25658428|accessdate=2014-06-30|mask=FFFF|units=SI}}</ref>
| Entropy = 38.83 J/mol·K<ref name=nist />
| HeatCapacity = 40.442 J/mol·K<ref name=nist />
  }}
|Section8={{Chembox Related
| OtherAnions = 
| OtherCations = 
| OtherCpds = [[碳化钽]]<br> [[碳化铌]]<br> [[碳化锆]]
 }}
}}

'''一氮化锆'''是一种[[无机化合物]]，化学式为<chem>ZrN</chem>。

==性质==
通过[[物理气相沉积]]（PVD）生长的氮化锆是类似金单质的浅金色。一氮化锆在室温下的[[电阻率]]为12.0µΩ·cm，[[温度系数]]5.6·10<sup>−8</sup>Ω·cm/K，[[超导]]转变温度10.4K，晶格参数a=0.4575nm。单晶氮化锆的[[材料硬度]]为22.7±1.7GPa，[[弹性模量]]450GPa。<ref>{{Cite journal | doi = 10.1116/1.4825349| title = Physical properties of epitaxial ZrN/MgO(001) layers grown by reactive magnetron sputtering| journal = Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films| volume = 31| issue = 6| pages = 061516| year = 2013| last1 = Mei | first1 = A. B.| last2 = Howe | first2 = B. M.| last3 = Zhang | first3 = C.| last4 = Sardela | first4 = M.| last5 = Eckstein | first5 = J. N.| last6 = Hultman | first6 = L.| last7 = Rockett | first7 = A.| last8 = Petrov | first8 = I.| last9 = Greene | first9 = J. E.
}}</ref>

==用处==
[[File:Zirconiun nitride coated cutters..JPG|thumb|left|300px|氮化锆涂层刀具]]
一氮化锆是一种类似于[[氮化钛]]的硬质陶瓷材料，是一种类似水泥的[[耐火材料]]。因此，它用于[[耐火材料]]、{{le|金属陶瓷|Cermet}}和实验室[[坩埚]]。当使用[[物理气相沉积]]涂层工艺进行应用时，它通常用于对医疗设备<ref>{{cite web|url = http://www.ionfusion.com|title = IonFusion Surgical|publisher = IonFusion Surgical, Inc.|access-date = 2014-06-30|archive-date = 2009-03-22|archive-url = https://web.archive.org/web/20090322032506/http://ionfusion.com/}}</ref>、工业部件（尤其是[[钻头]]）、汽车和航空航天部件以及其他易受高磨损和腐蚀环境影响的部件进行涂层。当与铝形成合金时，随着铝含量的增加，电子结构会从立方ZrN的局部八面体键发展成扭曲、更复杂的键和更高的硬度。<ref>Interface bonding of Zr1-xAlxN nanocomposites investigated by X-ray spectroscopies and first-principles calculations; M. Magnuson, W. Olovsson, N. Ghafoor, M. Oden, and L. Hultman;
Phys. Rev. Research 2, 013328 (2020). DOI: 10.1103/PhysRevResearch.2.013328</ref>

一氮化锆被建议用作火箭和飞机的[[过氧化氢]]燃料箱内衬。<ref>{{cite patent|number = 7736751}}</ref>

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==参考资料==
{{reflist}}

{{锆化合物}}
{{氮化物}}

[[Category:氮化物]]
[[Category:锆化合物]]
[[Category:超硬材料]]
[[Category:耐火材料]]
[[Category:氯化钠结构]]