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{{Chembox | ImageFile1 = Bromine-monofluoride-2D.png | ImageSize1 = 200px | ImageFile2 = Bromine-monofluoride-3D-vdW.png | ImageSize2 = 200px | IUPACName = Bromine fluoride | OtherNames = | Section1 = {{Chembox Identifiers | CASNo = 13863-59-7 | CASNo_Ref = {{cascite|correct|CAS}} | PubChem = | ChemSpiderID = 20474212 | SMILES = [F-].[Br] | InChI = 1/Br.FH/h;1H/p-1 | InChIKey = JDFDDPYVAPPVPX-REWHXWOFAP | StdInChI = 1S/Br.FH/h;1H/p-1 | StdInChIKey = JDFDDPYVAPPVPX-UHFFFAOYSA-M }} | Section2 = {{Chembox Properties | Formula = BrF | MolarMass = 98.903 | Appearance = 浅红色气体(≥ 20 °C)<ref name="HoWi">{{cite book | last=Holleman | first=Arnold F. | last2=Wiberg | first2=Egon | last3=Wiberg | first3=Nils | title=Lehrbuch der anorganischen Chemie | url=https://archive.org/details/lehrbuchderanorg0000arno | publication-place=Berlin | date=1995 | isbn=978-3-11-012641-9 | oclc=237142268 | language=de|page=[https://archive.org/details/lehrbuchderanorg0000arno/page/466 466]}}</ref><br/>棕色液体(< 20 °C)<ref name=crc/> | Density = 4.043 g/L <ref name=crc>{{cite book | last=Lide | first=David R. | title=CRC handbook of chemistry and physics : a ready-reference book of chemical and physical data. | publisher=CRC | publication-place=Boca Raton, Fla. | date=2008 | isbn=978-1-4200-6679-1 | oclc=302059515|page=4-53}}</ref> | MeltingPt = −33 °C <ref name=crc/> | BoilingPt = 20 °C (分解)<ref name=crc/> | Solubility = }} |Section3={{Chembox Structure |Dipole=1.29 D<ref>{{cite book | last=Emeléus | first=H. J. | title=The chemistry of fluorine and its compounds | publisher=Academic Press | publication-place=New York | date=1969 | isbn=978-1-4832-7304-4 | oclc=680138293|page=12}}</ref> }} |Section4={{Chembox Thermochemistry |DeltaHf=-94 kJ/mol<ref>{{cite book | last=Riedel | first=Erwin | last2=Janiak | first2=Christoph | title=Anorganische Chemie | publication-place=Berlin | date=2015 | isbn=978-3-11-035526-0 | oclc=893439425 | language=de|page=431}}</ref> }} | Section7 = {{Chembox Hazards | MainHazards = | FlashPt = | Autoignition = }} }} '''一氟化溴'''是一种很不稳定的[[卤素互化物]],化学式为BrF。它可由[[三氟化溴]]与[[五氟化溴]]与溴单质反应制得,可以用[[光谱]]检测到,但不能分离出来:<ref name=":0">{{cite book | last=Macintyre | first=J. E. | author2=Chapman and Hall | title=Dictionary of inorganic compounds | url=https://archive.org/details/dictionaryofinor0004unse | publisher=Chapman & Hall | publication-place=London | date=1992 | isbn=0-412-30120-2 | oclc=26338506|page=[https://archive.org/details/dictionaryofinor0004unse/page/285 285]}}</ref> :<math>\rm \ BrF_3 + Br_2 \rightarrow 3BrF</math> :<math>\rm \ BrF_5 + 2Br_2 \rightarrow 5BrF</math> 因为它在常温下就会发生歧化。一氟化溴是溴化剂。<ref name=":0"/> ==参考资料== {{reflist}} {{卤族元素互化物}} {{无机化合物小作品}} [[Category:氟化物]] [[Category:溴化合物]] [[Category:互卤化物]] [[Category:双原子分子]]
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